Synthesis and structure of (Rb{sub 0.50}Ba{sub 0.25})[UO{sub 2}(CH{sub 3}COO){sub 3}]
Journal Article
·
· Crystallography Reports
- Russian Academy of Sciences, Institute of Inorganic Chemistry, Siberian Branch (Russian Federation)
- Samara State University (Russian Federation)
A new compound (Rb{sub 0.50}Ba{sub 0.25})[UO{sub 2}(CH{sub 3}COO){sub 3}] is synthesized and its crystal structure is studied by X-ray diffraction. The compound crystallizes in the form of yellow plates belonging to the cubic crystal system. The unit cell parameter a = 17.0367(1) A, V = 4944.89(5) A{sup 3}, space group I 4 bar 3d, Z = 16, and R = 0.0182. The coordination polyhedron of the uranium atom is a hexagonal bipyramid with oxygen atoms of three acetate groups and the uranyl group in the vertices. The crystal chemical formula of the uranium-containing group is AB{sub 3}{sup 01}(A = UO{sub 2}{sup 2+}, B{sup 01} = CH{sub 3}COO{sup -}). The oxygen atoms of the acetate groups that enter the coordination polyhedron of uranium are bound to barium and rubidium atoms.
- OSTI ID:
- 22051227
- Journal Information:
- Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 2 Vol. 55; ISSN 1063-7745; ISSN CYSTE3
- Country of Publication:
- United States
- Language:
- English
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