Selective Valorization of CO2 towards Valuable Hydrocarbons through Methanol-mediated Tandem Catalysis

Mahnaz, Fatima; Dunlap, Violet; Helmer, Ryan; Borkar, Siddhesh Shirish; Navar, Ricardo; Yang, Xiaokun; Shetty, Manish

doi:10.1002/cctc.202300402

Selective Valorization of CO₂ towards Valuable Hydrocarbons through Methanol-mediated Tandem Catalysis

Journal Article · Fri Jul 07 00:00:00 EDT 2023 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.202300402· OSTI ID:2205058

^[1]; Dunlap, Violet ^[1]; ^[1]; ^[1]; ^[2]; ^[2]; ^[1]

Texas A & M Univ., College Station, TX (United States)
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

The thermocatalytic conversion of carbon dioxide (CO₂) into valuable hydrocarbons presents a promising solution for mitigating anthropogenic CO₂ emissions while producing drop-in replacements for fossil-derived products. Among the two tandem mechanisms for the direct hydrogenation of CO₂, the methanol synthesis coupled with the methanol to hydrocarbon (MTH) reaction offers an improvement over the reverse water-gas shift coupled with Fischer-Tropsch synthesis reaction (RWGS-FTS), as it is not limited by Anderson-Schulz-Flory distribution and yields higher selectivity towards specific products (e.g., olefins, aromatics, higher hydrocarbons). Herein, we focus on the recent progress achieved through this pathway and outline the existing knowledge gaps. We discuss the challenges involved in the process and highlight the key descriptors in the selection of catalyst components. Finally, we present several potential solutions to circumvent the current challenges, aiming to expedite the advancement of this route toward an efficient CO₂ hydrogenation process.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 2205058

Report Number(s):: LA-UR--23-26528

Journal Information:: ChemCatChem, Journal Name: ChemCatChem Journal Issue: 17 Vol. 15; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
C−C coupling
carbon dioxide hydrogenation
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methanol route
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zeolites

Selective Valorization of CO2 towards Valuable Hydrocarbons through Methanol-mediated Tandem Catalysis

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Selective Valorization of CO₂ towards Valuable Hydrocarbons through Methanol-mediated Tandem Catalysis