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Minimizing the impacts of the ammonia economy on the nitrogen cycle and climate

Journal Article · · Proceedings of the National Academy of Sciences of the United States of America
 [1];  [2];  [3];  [4];  [5];  [2];  [6];  [2];  [7];  [8];  [8];  [1]
  1. High Meadows Environmental Institute, Princeton University, Princeton, NJ 08544, Department of Civil and Environmental Engineering, Princeton University, Princeton, NJ 08544
  2. Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544
  3. Applied Materials and Sustainability Sciences, Princeton Plasma Physics Laboratory, Princeton, NJ 08540
  4. Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544, Applied Materials and Sustainability Sciences, Princeton Plasma Physics Laboratory, Princeton, NJ 08540, Andlinger Center for Energy and the Environment, Princeton University, Princeton, NJ 08544
  5. Andlinger Center for Energy and the Environment, Princeton University, Princeton, NJ 08544
  6. School of Aerospace Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0150
  7. Department of Chemical and Biological Engineering, Princeton University, Princeton, NJ 08544
  8. Department of Civil and Environmental Engineering, Princeton University, Princeton, NJ 08544

Ammonia (NH 3 ) is an attractive low-carbon fuel and hydrogen carrier. However, losses and inefficiencies across the value chain could result in reactive nitrogen emissions (NH 3 , NO x , and N 2 O), negatively impacting air quality, the environment, human health, and climate. A relatively robust ammonia economy (30 EJ/y) could perturb the global nitrogen cycle by up to 65 Mt/y with a 5% nitrogen loss rate, equivalent to 50% of the current global perturbation caused by fertilizers. Moreover, the emission rate of nitrous oxide (N 2 O), a potent greenhouse gas and ozone-depleting molecule, determines whether ammonia combustion has a greenhouse footprint comparable to renewable energy sources or higher than coal (100 to 1,400 gCO 2 e/kWh). The success of the ammonia economy hence hinges on adopting optimal practices and technologies that minimize reactive nitrogen emissions. We discuss how this constraint should be included in the ongoing broad engineering research to reduce environmental concerns and prevent the lock-in of high-leakage practices.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0023357; SC0021135
OSTI ID:
2204760
Alternate ID(s):
OSTI ID: 2217307
Journal Information:
Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 46 Vol. 120; ISSN 0027-8424
Publisher:
Proceedings of the National Academy of SciencesCopyright Statement
Country of Publication:
United States
Language:
English

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