Angular and energy distribution of fragment ions in dissociative double photoionization of acetylene molecules at 39 eV

Journal Article · Mon May 28 04:00:00 EDT 2012 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4720350· OSTI ID:22047215

Alagia, M ^[1]; Callegari, C; Richter, R ^[2]; Candori, P; Falcinelli, S; Vecchiocattivi, F ^[3]; Pirani, F ^[4]; Stranges, S ^[1]

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1. IOM CNR Laboratorio TASC, I-34012 Trieste (Italy)
2. Sincrotrone Trieste, Area Science Park, 34149 Basovizza, Trieste (Italy)
3. Dipartimento di Ingegneria Civile ed Ambientale, 06125 Perugia (Italy)
4. Dipartimento di Chimica dell'Universita di Perugia, 06123 Perugia (Italy)

The two-body dissociation reactions of the dication, C{sub 2}H{sub 2}{sup 2+}, produced by 39.0 eV double photoionization of acetylene molecules, have been studied by coupling photoelectron-photoion-photoion coincidence and ion imaging techniques. The results provide the kinetic energy and angular distributions of product ions. The analysis of the results indicates that the dissociation leading to C{sub 2}H{sup +}+H{sup +} products occurs through a metastable dication with a lifetime of 108 {+-} 22 ns, and a kinetic energy release (KER) distribution exhibiting a maximum at {approx}4.3 eV with a full width at half maximum (FWHM) of about 60%. The reaction leading to CH{sub 2}{sup +}+C{sup +} occurs in a time shorter than the typical rotational period of the acetylene molecules (of the order of 10{sup -12} s). The KER distribution of product ions for this reaction, exhibits a maximum at {approx}4.5 eV with a FWHM of about 28%. The symmetric dissociation, leading to CH{sup +} + CH{sup +}, exhibits a KER distribution with a maximum at {approx}5.2 eV with a FWHM of 44%. For the first two reactions the angular distributions of ion products also indicate that the double photoionization of acetylene occurs when the neutral molecule is mainly oriented perpendicularly to the light polarization vector.

• OSTI ID: 22047215
• Journal Information: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 20 Vol. 136; ISSN JCPSA6; ISSN 0021-9606
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ACETYLENE
ANGULAR DISTRIBUTION
DISSOCIATION
ENERGY SPECTRA
KINETIC ENERGY
METASTABLE STATES
PHOTOIONIZATION
PHOTOLYSIS
PHOTON-MOLECULE COLLISIONS
POLARIZATION
REACTION KINETICS
ROTATIONAL STATES