Promoting reversibility of layered potassium cathode through interstitial doping

Xu, Xuan; Li, Xun-Lu; Rahman, Muhammad Mominur; Bao, Jian; Luo, Rui-Jie; Ma, Cui; Du, Chong-Yu; Zeng, Jie; Mei, Zhe; Qian, Zhe; Hu, Enyuan; Zhou, Yong-Ning

doi:10.1016/j.cej.2023.147021

Title: Promoting reversibility of layered potassium cathode through interstitial doping

Journal Article · Mon Oct 30 00:00:00 EDT 2023 · Chemical Engineering Journal

DOI:https://doi.org/10.1016/j.cej.2023.147021· OSTI ID:2204632

Xu, Xuan ^[1];

^[2];

^[3]; Bao, Jian ^[1]; Luo, Rui-Jie ^[1]; Ma, Cui ^[1]; Du, Chong-Yu ^[1]; Zeng, Jie ^[1]; Mei, Zhe ^[1]; Qian, Zhe ^[1]; Hu, Enyuan ^[3];

^[1]

Fudan Univ., Shanghai (China)
Shanghai Jiao Tong Univ. (China)
Brookhaven National Laboratory (BNL), Upton, NY (United States)

With the increasing needs for large-scale and low-cost energy storage devices, Mn-based layered oxide cathodes have achieved considerable researching interests for potassium-ion batteries owing to their high energy density, abundant resource and low toxicity. However, their developments are challenged by the absence of suitable cathode materials to tolerate large-sized K-ion insertion/extraction and the presence of Jahn-Teller distortion of Mn³⁺. To address this issue, here we present a strategy of embedding boron into interstitial tetrahedral sites to obtain a P3-K_0.5Mn_0.8Co_0.2B_0.1O₂ cathode. Strong B-O covalent bonds facilitate the construction of robust orthorhombic framework and alleviate the undesired elongation of Mn-O bonds, contributing to excellent electrochemical performance. In addition, boron ions are verified to promote the formation of a homogeneous cathode electrolyte interphase layer, improving interfacial stability and realizing highly reversible cycling in a wide voltage range (1.4-4.3 V). This strategy provides a new pathway towards the development of high-performance cathode materials for potassium-ion batteries.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: SC0012704; 52071085; 52101242

OSTI ID:: 2204632

Report Number(s):: BNL-224961-2023-JAAM

Journal Information:: Chemical Engineering Journal, Vol. 477; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
Potassium-ion batteries
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Interstitial doping
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Title: Promoting reversibility of layered potassium cathode through interstitial doping

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