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Structuring Nutrient Yields throughout Mississippi/Atchafalaya River Basin Using Machine Learning Approaches

Journal Article · · Environments (Online)
 [1];  [2];  [3]
  1. Southern University at New Orleans, LA (United States)
  2. Montclair State University, NJ (United States)
  3. Brookhaven National Laboratory (BNL), Upton, NY (United States)

To minimize the eutrophication pressure along the Gulf of Mexico or reduce the size of the hypoxic zone in the Gulf of Mexico, it is important to understand the underlying temporal and spatial variations and correlations in excess nutrient loads, which are strongly associated with the formation of hypoxia. This study’s objective was to reveal and visualize structures in high-dimensional datasets of nutrient yield distributions throughout the Mississippi/Atchafalaya River Basin (MARB). For this purpose, the annual mean nutrient concentrations were collected from thirty-three US Geological Survey (USGS) water stations scattered in the upper and lower MARB from 1996 to 2020. Eight surface water quality indicators were selected to make comparisons among water stations along the MARB over the past two decades. Principal component analysis (PCA) was used to comprehensively evaluate the nutrient yields across thirty-three USGS monitoring stations and identify the major contributing nutrient loads. The results showed that all samples could be analyzed using two main components, which accounted for 81.6% of the total variance. The PCA results showed that yields of orthophosphate (OP), silica (SI), nitrate–nitrites (NO3-NO2), and total suspended sediment (TSS) are major contributors to nutrient yields. It also showed that land-planted crops, density of population, domestic and industrial discharges, and precipitation are fundamental causes of excess nutrient loads in MARB. These factors are of great significance for the excess nutrient load management and pollution control of the Mississippi River. It was found that the average nutrient yields were stable within the sub-MARB area, but the large nitrogen yields in the upper MARB and the large phosphorus yields in the lower MARB were of great concern. t-distributed stochastic neighbor embedding (t-SNE) revealed interesting nonlinear and local structures in nutrient yield distributions. Clustering analysis (CA) showed the detailed development of similarities in the nutrient yield distribution. Moreover, PCA, t-SNE, and CA showed consistent clustering results. This study demonstrated that the integration of dimension reduction techniques, PCA, and t-SNE with CA techniques in machine learning are effective tools for the visualization of the structures of the correlations in high-dimensional datasets of nutrient yields and provide a comprehensive understanding of the correlations in the distributions of nutrient loads across the MARB.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS)
Grant/Contract Number:
SC0012704
OSTI ID:
2204136
Report Number(s):
BNL--224924-2023-JAAM
Journal Information:
Environments (Online), Journal Name: Environments (Online) Journal Issue: 9 Vol. 10; ISSN 2076-3298
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
English

References (30)

Introduction to HPC with MPI for Data Science book January 2016
Use of water quality index and multivariate statistical techniques for the assessment of spatial variations in water quality of a small river journal November 2018
Modeling runoff–sediment response to land use/land cover changes using integrated GIS and SWAT model in the Beressa watershed journal August 2017
Bayesian decision analysis for environmental and resource management journal January 1997
Seasonal differences in trace element concentrations and distribution in Spartina alterniflora root tissue journal August 2018
Effect of land use types on stream water quality under seasonal variation and topographic characteristics in the Wei River basin, China journal January 2016
Estimation of nutrient (N and P) fluxes into Newark Bay, USA journal May 2023
Using hysteresis analysis of high-resolution water quality monitoring data, including uncertainty, to infer controls on nutrient and sediment transfer in catchments journal February 2016
Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India)—a case study journal November 2004
Analysis of a complex of statistical variables into principal components. journal January 1933
Silicon increases the phosphorus availability of Arctic soils journal January 2019
Water quality assessment based on multivariate statistics and water quality index of a strategic river in the Brazilian Atlantic Forest journal December 2020
Nanoscale measurement of trace element distributions in Spartina alterniflora root tissue during dormancy journal January 2017
Trend analysis of nutrient loadings in a large prairie catchment journal December 2016
Power-law stochastic neighbor embedding conference March 2017
Nitrogen and Phosphorus Sources and Delivery from the Mississippi/Atchafalaya River Basin: An Update Using 2012 SPARROW Models journal February 2021
Incorporating Uncertainty Into the Ranking of SPARROW Model Nutrient Yields From Mississippi/Atchafalaya River Basin Watersheds journal April 2009
Spatial Variability in Nutrient Transport by HUC8, State, and Subbasin Based on Mississippi/Atchafalaya River Basin SPARROW Models journal January 2014
A Study Of A Measure Of Sampling Adequacy For Factor-Analytic Correlation Matrices journal January 1977
On Information and Sufficiency journal March 1951
Characterisation and assessment of spatiotemporal variations in nutrient concentrations and fluxes in an urban watershed: Passaic River Basin, New Jersey, USA journal January 2018
Sources of Nitrate Yields in the Mississippi River Basin journal January 2010
A Spatial Analysis of Phosphorus in the Mississippi River Basin journal May 2011
SPARROW Models Used to Understand Nutrient Sources in the Mississippi/Atchafalaya River Basin journal September 2013
Statistical tools for water quality assessment and monitoring in river ecosystems – a scoping review and recommendations for data analysis journal February 2022
Using Principal Components Analysis and IDW Interpolation to Determine Spatial and Temporal Changes of Surface Water Quality of Xin’anjiang River in Huangshan, China journal April 2020
Simple Prediction of an Ecosystem-Specific Water Quality Index and the Water Quality Classification of a Highly Polluted River through Supervised Machine Learning journal April 2022
Trends in the nutrient enrichment of U.S. rivers during the late 20th century and their relation to changes in probable stream trophic conditions journal January 2006
Statistical and trend analysis of water quality and quantity data for the Strymon River in Greece journal December 2001
The Gulf of Mexico: An Overview journal March 2021