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Mechanisms and models for water transport in reverse osmosis membranes: history, critical assessment, and recent developments

Journal Article · · Chemical Society Reviews
DOI:https://doi.org/10.1039/D3CS00395G· OSTI ID:2203971
 [1];  [2];  [3];  [4];  [2]
  1. Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06520-8286, USA, Department of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, North Carolina 27695-7910, USA
  2. Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06520-8286, USA
  3. Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06520-8286, USA, College of Environmental Science and Engineering, Tongji University, Shanghai, China
  4. CAS Key Laboratory of Urban Pollutant Conversion, Department of Environmental Science and Engineering, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230026, China

Water scarcity is one of the greatest societal challenges facing humanity.

Research Organization:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC)
Grant/Contract Number:
SC0019112
OSTI ID:
2203971
Alternate ID(s):
OSTI ID: 2578213
Journal Information:
Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 24 Vol. 52; ISSN 0306-0012; ISSN CSRVBR
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (99)

Membrane Technology and Applications book July 2012
Studies of intramembrane transport: A phenomenological approach journal January 1968
Water and ion flow across cellulosic membranes journal March 1959
Transport properties of cellulose acetate osmotic membranes journal April 1965
Pressure-induced diffusion of organic liquids through highly swollen polymer membranes journal September 1970
Influence of compacting pressure on the permeability of vectorized membranes for liquids journal June 1971
The mechanism of liquid transport through swollen polymer membranes journal September 1971
Studies on elastic hydrogel membrane. I. Effect of preparation conditions on the membrane performance journal August 1989
Steady-state distribution of water in cellulose acetate membrane journal January 1969
Diffusive and hydraulic permeabilities of water in water-swollen polymer membranes journal June 1971
Comments on the relation between hydraulic permeability and diffusion in homogeneous swollen membranes journal June 1974
Théorie Cinétique des Lois de la Pression Osmotique des Électrolytes Forts journal January 1923
Understanding Non-equilibrium Thermodynamics book January 2008
Basic Principles of Membrane Technology book January 1996
Thermodynamic analysis of the permeability of biological membranes to non-electrolytes journal January 1958
On the mechanism of desalination by reversed osmotic flow through cellulose acetate membranes journal August 1966
Composite reverse osmosis and nanofiltration membranes journal August 1993
On liquid diffusion journal March 1995
The solution-diffusion model: a review journal November 1995
Modelling the performance of membrane nanofiltration—critical assessment and model development journal April 2002
Transport coefficients and salt rejection in unchanged hyperfiltration membranes journal December 1966
Reverse osmosis desalination costs derived from the Coalinga pilot plant operation journal January 1967
The early history of reverse osmosis membrane development journal September 1998
Modelling reverse osmosis by irreversible thermodynamics journal April 1998
Energy analysis and efficiency assessment of reverse osmosis desalination process journal August 2011
Techniques for characterization of polyamide thin film composite membranes journal November 2011
Progress in transport theory and characterization method of Reverse Osmosis (RO) membrane in past fifty years journal May 2018
True driving force and characteristics of water transport in osmotic membranes journal December 2021
Theory for salt transport in charged reverse osmosis membranes: Novel analytical equations for desalination performance and experimental validation journal July 2023
Two-fluid model for the simultaneous flow of colloids and fluids in porous media journal March 2011
New parametrization method for salt permeability of reverse osmosis desalination membranes journal May 2022
Reformulation of the solution-diffusion theory of reverse osmosis journal October 2004
The porous structure of the fully-aromatic polyamide film in reverse osmosis membranes journal February 2015
Probing the internal structure of reverse osmosis membranes by positron annihilation spectroscopy: Gaining more insight into the transport of water and small solutes journal July 2015
Investigating the void structure of the polyamide active layers of thin-film composite membranes journal January 2016
Micro-to nano-scale characterisation of polyamide structures of the SW30HR RO membrane using advanced electron microscopy and stain tracers journal December 2016
Tutorial review of reverse osmosis and electrodialysis journal April 2022
A mechanistic model for salt and water transport in leaky membranes: Implications for low-salt-rejection reverse osmosis membranes journal July 2023
Solution-diffusion-electromigration approximation model (SDE-A) for strongly charged, weakly charged and effectively uncharged reverse osmosis membranes journal August 2023
In situ formation of silver nanoparticles on thin-film composite reverse osmosis membranes for biofouling mitigation journal October 2014
Minimal and zero liquid discharge with reverse osmosis using low-salt-rejection membranes journal March 2020
Diffusion: Mass Transfer in Fluid Systems book January 2009
Stokes flow through periodic arrays of spheres journal February 1982
Salt and Water Transport in Reverse Osmosis Membranes: Beyond the Solution-Diffusion Model journal December 2021
Molecular Simulations to Elucidate Transport Phenomena in Polymeric Membranes journal March 2022
Significance of Co-ion Partitioning in Salt Transport through Polyamide Reverse Osmosis Membranes journal February 2023
Derivation of the Theoretical Minimum Energy of Separation of Desalination Processes journal November 2020
Aromatic Polyamide Reverse-Osmosis Membrane: An Atomistic Molecular Dynamics Simulation journal September 2016
Water Flow inside Polamide Reverse Osmosis Membranes: A Non-Equilibrium Molecular Dynamics Study journal February 2017
Molecular Structure of Aromatic Reverse Osmosis Polyamide Barrier Layers journal March 2019
Pathways and Challenges for Biomimetic Desalination Membranes with Sub-Nanometer Channels journal September 2020
Nanofluidic Transport Theory with Enhancement Factors Approaching One journal December 2019
Sea Water Demineralization by Means of an Osmotic Membrane book January 1963
Ultrafilter Membranes and Ultrafiltration. journal June 1936
Positron Annihilation Spectroscopic Evidence to Demonstrate the Flux-Enhancement Mechanism in Morphology-Controlled Thin-Film-Composite (TFC) Membrane journal March 2005
Quantification of Functional Groups and Modeling of Their Ionization Behavior in the Active Layer of FT30 Reverse Osmosis Membrane journal July 2008
On the Permeation of Cellophane Membranes by Diffusion journal December 1958
Intercrystalline Channels at Subnanometer Scale for Precise Molecular Nanofiltration journal July 2023
Correlation Study between Free-Volume Holes and Molecular Separations of Composite Membranes for Reverse Osmosis Processes by Means of Variable-Energy Positron Annihilation Techniques journal August 2011
Why Are Carbon Nanotubes Fast Transporters of Water? journal February 2008
Molecular Origin of Fast Water Transport in Carbon Nanotube Membranes: Superlubricity versus Curvature Dependent Friction journal October 2010
Materials for next-generation desalination and water purification membranes journal April 2016
Science and technology for water purification in the coming decades journal March 2008
Massive radius-dependent flow slippage in carbon nanotubes journal September 2016
Future global urban water scarcity and potential solutions journal August 2021
Nanofluidics, from bulk to interfaces journal January 2010
Antifouling membranes for sustainable water purification: strategies and mechanisms journal January 2016
111 years of Brownian motion journal January 2016
Fabrication of desalination membranes by interfacial polymerization: history, current efforts, and future directions journal January 2021
The relative insignificance of advanced materials in enhancing the energy efficiency of desalination technologies journal January 2020
A computational investigation of the properties of a reverse osmosis membrane journal January 2010
Binary Diffusion and Bulk Flow through a Potential-Energy Profile: A Kinetic Basis for the Thermodynamic Equations of Flow through Membranes journal September 1968
Multimodel assessment of water scarcity under climate change journal December 2013
Electron tomography reveals details of the internal microstructure of desalination membranes journal August 2018
Thermodynamic Modeling of Solute Transport Through Reverse Osmosis Membrane journal July 2000
Review of Reverse Osmosis Membranes and Transport Models journal November 1981
X-ray Scattering Studies of Reverse Osmosis Materials journal August 2020
Reciprocal Relations in Irreversible Processes. I. journal February 1931
Reciprocal Relations in Irreversible Processes. II. journal December 1931
Theory of Ion and Water Transport in Reverse-Osmosis Membranes journal February 2018
Structured and viscous water in subnanometer gaps journal March 2007
Modified Lucas-Washburn theory for fluid filling in nanotubes journal May 2022
Hydrodynamic boundary conditions, correlation functions, and Kubo relations for confined fluids journal April 1994
Revisiting Sampson's theory for hydrodynamic transport in ultrathin nanopores journal October 2020
The compleat Darcy: New lessons learned from the first English translation of les fontaines publiques de la Ville de Dijon journal May 2005
Mechanism and performance relevance of nanomorphogenesis in polyamide films revealed by quantitative 3D imaging and machine learning journal February 2022
Water transport in reverse osmosis membranes is governed by pore flow, not a solution-diffusion mechanism journal April 2023
Fluidity of Bound Hydration Layers journal August 2002
The Future of Seawater Desalination: Energy, Technology, and the Environment journal August 2011
Designing the Next Generation of Chemical Separation Membranes journal May 2011
Nature of Solvent Transfer in Osmosis journal August 1957
Prediction of Ultrafiltration Membrane Performance journal October 1962
Osmotic Flow in a Rigid Porous Membrane journal August 1965
Maximizing the right stuff: The trade-off between membrane permeability and selectivity journal June 2017
Nanoscale control of internal inhomogeneity enhances water transport in desalination membranes journal January 2021
A two-phase model that unifies and extends the classical models of membrane transport journal July 2022
Passage of Molecules Through Capillary Walls journal July 1953
The global challenge for adequate and safe water journal February 2006
Theory of expansion and compression of polymeric materials preprint January 2023

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