ON THE RELEVANCE OF POLYYNYL-SUBSTITUTED POLYCYCLIC AROMATIC HYDROCARBONS TO ASTROPHYSICS

Journal Article · Sun Jun 10 04:00:00 EDT 2012 · Astrophysical Journal

DOI:https://doi.org/10.1088/0004-637X/752/1/25· OSTI ID:22039433

Rouille, G; Steglich, M; Carpentier, Y; Jaeger, C; Huisken, F ^[1]; Henning, Th ^[2]; Czerwonka, R; Theumer, G; Boerger, C; Bauer, I

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1. Laboratory Astrophysics Group of the Max Planck Institute for Astronomy at the Friedrich Schiller University Jena, Institute of Solid State Physics, Helmholtzweg 3, D-07743 Jena (Germany)
2. Max Planck Institute for Astronomy, Koenigstuhl 17, D-69117 Heidelberg (Germany)

We report on the absorption spectra of the polycyclic aromatic hydrocarbon (PAH) molecules anthracene, phenanthrene, and pyrene carrying either an ethynyl (-C{sub 2}H) or a butadiynyl (-C{sub 4}H) group. Measurements were carried out in the mid-infrared at room temperature on grains embedded in CsI pellets and in the near-ultraviolet at cryogenic temperature on molecules isolated in Ne matrices. The infrared measurements show that interstellar populations of polyynyl-substituted PAHs would give rise to collective features in the same way as non-substituted PAHs give rise to the aromatic infrared bands. The main features characteristic of the substituted molecules correspond to the acetylenic CH stretching mode near 3.05 {mu}m and to the almost isoenergetic acetylenic CCH in- and out-of-plane bending modes near 15.9 {mu}m. Sub-populations defined by the length of the polyynyl side group cause collective features which correspond to the various acetylenic CC stretching modes. The ultraviolet spectra reveal that the addition of an ethynyl group to a non-substituted PAH molecule results in all of its electronic transitions being redshifted. Due to fast internal energy conversion, the bands at shorter wavelengths are significantly broadened. Those at longer wavelengths are only barely affected in this respect. As a consequence, their relative peak absorption increases. The substitution with the longer butadiynyl chain causes the same effects with a larger magnitude, resulting in the spectra showing a prominent if not dominating {pi}-{pi}* transition at long wavelengths. After discussing the relevance of polyynyl-substituted PAHs to astrophysics, we conclude that this class of highly conjugated, unsaturated molecules represents valid candidates for the carriers of the diffuse interstellar bands.

• OSTI ID: 22039433
• Journal Information: Astrophysical Journal, Journal Name: Astrophysical Journal Journal Issue: 1 Vol. 752; ISSN ASJOAB; ISSN 0004-637X
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
79 ASTRONOMY AND ASTROPHYSICS
ABSORPTION SPECTRA
ANTHRACENE
ENERGY CONVERSION
INTERMEDIATE INFRARED RADIATION
MOLECULES
PHENANTHRENE
POLYCYCLIC AROMATIC HYDROCARBONS
PYRENE
ULTRAVIOLET RADIATION
ULTRAVIOLET SPECTRA