Stabilizing lithium plating in polymer electrolytes by concentration-polarization-induced phase transformation

Cheng, Qian; Jin, Tianwei; Miao, Yupeng; Liu, Zhe; Borovilas, James; Zhang, Hanrui; Liu, Shuwei; Kim, So-Yeon; Zhang, Ruiwen; Wang, Haozhen; Chen, Xi; Chen, Long-Qing; Li, Ju; Min, Wei; Yang, Yuan

doi:10.1016/j.joule.2022.08.001

Stabilizing lithium plating in polymer electrolytes by concentration-polarization-induced phase transformation

Journal Article · Sat Oct 01 00:00:00 EDT 2022 · Joule

DOI:https://doi.org/10.1016/j.joule.2022.08.001· OSTI ID:2203147

Cheng, Qian; Jin, Tianwei; Miao, Yupeng; Liu, Zhe; Borovilas, James; Zhang, Hanrui; Liu, Shuwei; Kim, So-Yeon; Zhang, Ruiwen; Wang, Haozhen; Chen, Xi; Chen, Long-Qing; Li, Ju; Min, Wei; Yang, Yuan

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Research Organization:: Michigan State Univ., East Lansing, MI (United States)

Sponsoring Organization:: National Science Foundation (NSF); US Air Force Office of Scientific Research (AFOSR); US Army Research Office (ARO); US Department of the Navy, Office of Naval Research (ONR); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007803

OSTI ID:: 2203147

Alternate ID(s):: OSTI ID: 2418011
OSTI ID: 1895506

Journal Information:: Joule, Journal Name: Joule Journal Issue: 10 Vol. 6; ISSN 2542-4351

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (59)

Fabrication and Properties of Composites of Poly(ethylene oxide) and Functionalized Carbon Nanotubes Geng, H. Z.; Rosen, R.; Zheng, B. Advanced Materials, Vol. 14, Issue 19 https://doi.org/10.1002/1521-4095(20021002)14:19<1387::AID-ADMA1387>3.0.CO;2-Q	journal	October 2002
Homogeneous and Fast Ion Conduction of PEO‐Based Solid‐State Electrolyte at Low Temperature Xu, Shengjun; Sun, Zhenhua; Sun, Chengguo Advanced Functional Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adfm.202007172	journal	September 2020
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte Lu, Qingwen; He, Yan-Bing; Yu, Qipeng Advanced Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adma.201604460	journal	February 2017
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Imaging Chemical Kinetics of Radical Polymerization with an Ultrafast Coherent Raman Microscope Li, Haozheng; Cheng, Yong; Tang, Huajun Advanced Science, Vol. 7, Issue 10 https://doi.org/10.1002/advs.201903644	journal	March 2020
Deciphering the Reaction Mechanism of Lithium–Sulfur Batteries by In Situ/Operando Synchrotron‐Based Characterization Techniques Yan, Yingying; Cheng, Chen; Zhang, Liang Advanced Energy Materials, Vol. 9, Issue 18 https://doi.org/10.1002/aenm.201900148	journal	March 2019
Commercialization of Lithium Battery Technologies for Electric Vehicles Zeng, Xiaoqiao; Li, Matthew; Abd El‐Hady, Deia Advanced Energy Materials, Vol. 9, Issue 27 https://doi.org/10.1002/aenm.201900161	journal	June 2019
Dendritic growth mechanisms in lithium/polymer cells Brissot, C.; Rosso, M.; Chazalviel, J. -N. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(98)00242-0	journal	September 1999
Vibrational spectra of succinonitrile and its [1,4-13C2]-, [2,2,3,3-2H4]- and [1,4-13C2-2,2,3,3-2H4]-isotopomers and a force field of succinonitrile Fengler, O. I.; Ruoff, A. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 57, Issue 1 https://doi.org/10.1016/S1386-1425(00)00338-3	journal	January 2001
Mechanical properties of metallic lithium: from nano to bulk scales Fincher, Cole D.; Ojeda, Daniela; Zhang, Yuwei Acta Materialia, Vol. 186 https://doi.org/10.1016/j.actamat.2019.12.036	journal	March 2020
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.05.002	journal	August 2018
Phase segregation phenomena in poly(ethylene oxide):LiN(CF3SO2)2 electrolyte studied by local Raman spectroscopy Marzantowicz, M.; Dygas, J. R.; Krok, F. Electrochimica Acta, Vol. 55, Issue 19 https://doi.org/10.1016/j.electacta.2010.04.043	journal	July 2010
Effects of Nano Alumina and Plasticizers on Morphology, Ionic Conductivity, Thermal and Mechanical Properties of PEO-LiCF3SO3 Solid Polymer Electrolyte Klongkan, Sasithorn; Pumchusak, Jantrawan Electrochimica Acta, Vol. 161 https://doi.org/10.1016/j.electacta.2015.02.074	journal	April 2015
Anomalously high elastic modulus of a poly(ethylene oxide)-based composite electrolyte Yang, Guang; Lehmann, Michelle L.; Zhao, Sheng Energy Storage Materials, Vol. 35 https://doi.org/10.1016/j.ensm.2020.11.031	journal	March 2021
Investigation of mechanical properties of polyvinyl chloride–polyethylene oxide (PVC–PEO) based polymer electrolytes for lithium polymer cells Ramesh, S.; Winie, Tan; Arof, A. K. European Polymer Journal, Vol. 43, Issue 5 https://doi.org/10.1016/j.eurpolymj.2007.02.006	journal	May 2007
Effects of dimethyl or diethyl carbonate as an additive on volatility and flash point of an aviation fuel Li, Dan; Fang, Wenjun; Xing, Yan Journal of Hazardous Materials, Vol. 161, Issue 2-3 https://doi.org/10.1016/j.jhazmat.2008.04.070	journal	January 2009
A Superionic Conductive, Electrochemically Stable Dual-Salt Polymer Electrolyte Li, Si; Chen, Yu-Ming; Liang, Wenfeng Joule, Vol. 2, Issue 9 https://doi.org/10.1016/j.joule.2018.06.008	journal	September 2018
Effect of nano-silica filler in polymer electrolyte on Li dendrite formation in Li/poly(ethylene oxide)–Li(CF3SO2)2N/Li Liu, S.; Imanishi, N.; Zhang, T. Journal of Power Sources, Vol. 195, Issue 19 https://doi.org/10.1016/j.jpowsour.2010.04.027	journal	October 2010
Emerging applications of stimulated Raman scattering microscopy in materials science Cheng, Qian; Miao, Yupeng; Wild, Joseph Matter, Vol. 4, Issue 5 https://doi.org/10.1016/j.matt.2021.02.013	journal	May 2021
Ion-conductivity and Young's modulus of the polymer electrolyte PEO–ammonium perchlorate Maitra, M.; Sinha, M.; Mukhopadhyay, A. Solid State Ionics, Vol. 178, Issue 3-4 https://doi.org/10.1016/j.ssi.2007.01.006	journal	February 2007
Boussinesq's problem for a rigid cone Sneddon, Ian N. Mathematical Proceedings of the Cambridge Philosophical Society, Vol. 44, Issue 4 https://doi.org/10.1017/S0305004100024518	journal	October 1948
Shedding X-ray Light on the Interfacial Electrochemistry of Silicon Anodes for Li-Ion Batteries Cao, Chuntian; Shyam, Badri; Wang, Jiajun Accounts of Chemical Research, Vol. 52, Issue 9 https://doi.org/10.1021/acs.accounts.9b00233	journal	August 2019
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Resolving the Framework Position of Organic Structure-Directing Agents in Hierarchical Zeolites via Polarized Stimulated Raman Scattering Fleury, Guillaume; Steele, Julian A.; Gerber, Iann C. The Journal of Physical Chemistry Letters, Vol. 9, Issue 7 https://doi.org/10.1021/acs.jpclett.8b00399	journal	March 2018
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Regulating Key Variables and Visualizing Lithium Dendrite Growth: An Operando X-ray Study Yu, Seung-Ho; Huang, Xin; Brock, Joel D. Journal of the American Chemical Society, Vol. 141, Issue 21 https://doi.org/10.1021/jacs.8b13297	journal	May 2019
Effect of Molecular Weight and Salt Concentration on Conductivity of Block Copolymer Electrolytes Panday, Ashoutosh; Mullin, Scott; Gomez, Enrique D. Macromolecules, Vol. 42, Issue 13 https://doi.org/10.1021/ma900451e	journal	July 2009
Stabilizing lithium metal using ionic liquids for long-lived batteries Basile, A.; Bhatt, A. I.; O’Mullane, A. P. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11794	journal	June 2016
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
The plastic-crystalline phase of succinonitrile as a universal matrix for solid-state ionic conductors Alarco, Pierre-Jean; Abu-Lebdeh, Yaser; Abouimrane, Ali Nature Materials, Vol. 3, Issue 7 https://doi.org/10.1038/nmat1158	journal	June 2004
In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries Bhattacharyya, Rangeet; Key, Baris; Chen, Hailong Nature Materials, Vol. 9, Issue 6 https://doi.org/10.1038/nmat2764	journal	May 2010
7Li MRI of Li batteries reveals location of microstructural lithium Chandrashekar, S.; Trease, Nicole M.; Chang, Hee Jung Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3246	journal	February 2012
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Operando and three-dimensional visualization of anion depletion and lithium growth by stimulated Raman scattering microscopy Cheng, Qian; Wei, Lu; Liu, Zhe Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05289-z	journal	July 2018
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Stress-driven lithium dendrite growth mechanism and dendrite mitigation by electroplating on soft substrates Wang, Xu; Zeng, Wei; Hong, Liang Nature Energy, Vol. 3, Issue 3 https://doi.org/10.1038/s41560-018-0104-5	journal	March 2018
High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes Han, Fudong; Westover, Andrew S.; Yue, Jie Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-018-0312-z	journal	January 2019
Pathways for practical high-energy long-cycling lithium metal batteries Liu, Jun; Bao, Zhenan; Cui, Yi Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0338-x	journal	February 2019
Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries Zachman, Michael J.; Tu, Zhengyuan; Choudhury, Snehashis Nature, Vol. 560, Issue 7718 https://doi.org/10.1038/s41586-018-0397-3	journal	August 2018
Quantifying inactive lithium in lithium metal batteries Fang, Chengcheng; Li, Jinxing; Zhang, Minghao Nature, Vol. 572, Issue 7770 https://doi.org/10.1038/s41586-019-1481-z	journal	August 2019
Li metal deposition and stripping in a solid-state battery via Coble creep Chen, Yuming; Wang, Ziqiang; Li, Xiaoyan Nature, Vol. 578, Issue 7794 https://doi.org/10.1038/s41586-020-1972-y	journal	February 2020
Transition of lithium growth mechanisms in liquid electrolytes Bai, Peng; Li, Ju; Brushett, Fikile R. Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE01674J	journal	January 2016
Lithium dendrite growth mechanisms in polymer electrolytes and prevention strategies Barai, Pallab; Higa, Kenneth; Srinivasan, Venkat Physical Chemistry Chemical Physics, Vol. 19, Issue 31 https://doi.org/10.1039/C7CP03304D	journal	January 2017
Concentration and velocity profiles in a polymeric lithium-ion battery electrolyte Steinrück, Hans-Georg; Takacs, Christopher J.; Kim, Hong-Keun Energy & Environmental Science, Vol. 13, Issue 11 https://doi.org/10.1039/D0EE02193H	journal	January 2020
Stable solvates in solution of lithium bis(trifluoromethylsulfone)imide in glymes and other aprotic solvents: Phase diagrams, crystallography and Raman spectroscopyElectronic supplementary information (ESI) available: Crystallographic data (single crystal data) in cif format (CCDC reference number 184345). See http://www.rsc.org/suppdata/cp/b2/b203776a/ Brouillette, Dany; Irish, Donald E.; Taylor, Nicholas J. Physical Chemistry Chemical Physics, Vol. 4, Issue 24 https://doi.org/10.1039/b203776a	journal	November 2002
Molecular Vibrations and Structure of High Polymers. III. Polarized Infrared Spectra, Normal Vibrations, and Helical Conformation of Polyethylene Glycol Miyazawa, Tatsuo; Fukushima, Kunio; Ideguchi, Yoshiko The Journal of Chemical Physics, Vol. 37, Issue 12 https://doi.org/10.1063/1.1733103	journal	December 1962
A Unique Equation to Estimate Flash Points of Selected Pure Liquids Application to the Correction of Probably Erroneous Flash Point Values Catoire, Laurent; Naudet, Valérie Journal of Physical and Chemical Reference Data, Vol. 33, Issue 4 https://doi.org/10.1063/1.1835321	journal	December 2004
Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi Proceedings of the National Academy of Sciences, Vol. 113, Issue 26 https://doi.org/10.1073/pnas.1600422113	journal	June 2016
Measurement of the Young’s moduli of individual polyethylene oxide and glass nanofibres Bellan, Leon M.; Kameoka, Jun; Craighead, Harold G. Nanotechnology, Vol. 16, Issue 8 https://doi.org/10.1088/0957-4484/16/8/017	journal	May 2005
Electrochemical aspects of the generation of ramified metallic electrodeposits Chazalviel, J. -N. Physical Review A, Vol. 42, Issue 12 https://doi.org/10.1103/PhysRevA.42.7355	journal	December 1990
Label-Free Biomedical Imaging with High Sensitivity by Stimulated Raman Scattering Microscopy Freudiger, Christian W.; Min, Wei; Saar, Brian G. Science, Vol. 322, Issue 5909 https://doi.org/10.1126/science.1165758	journal	December 2008
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
How lithium dendrites form in liquid batteries Xiao, Jie Science, Vol. 366, Issue 6464 https://doi.org/10.1126/science.aay8672	journal	October 2019
Thermosensitive crystallization–boosted liquid thermocells for low-grade heat harvesting Yu, Boyang; Duan, Jiangjiang; Cong, Hengjiang Science, Vol. 370, Issue 6514 https://doi.org/10.1126/science.abd6749	journal	September 2020
In Situ Concentration Cartography in the Neighborhood of Dendrites Growing in Lithium/Polymer-Electrolyte/Lithium Cells Brissot, C. Journal of The Electrochemical Society, Vol. 146, Issue 12 https://doi.org/10.1149/1.1392649	journal	January 1999
Flammability of Li-Ion Battery Electrolytes: Flash Point and Self-Extinguishing Time Measurements Hess, Steffen; Wohlfahrt-Mehrens, Margret; Wachtler, Mario Journal of The Electrochemical Society, Vol. 162, Issue 2 https://doi.org/10.1149/2.0121502jes	journal	January 2015
Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries Stone, G. M.; Mullin, S. A.; Teran, A. A. Journal of The Electrochemical Society, Vol. 159, Issue 3 https://doi.org/10.1149/2.030203jes	journal	January 2012
Probing Electrolyte Solvents at Solid/Liquid Interface Using Gap-Mode Surface-Enhanced Raman Spectroscopy Yang, Guang; Sacci, Robert L.; Ivanov, Ilia N. Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0391902jes	journal	January 2019

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