Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol

Chen, Yuzhi; Zaveri, Rahul A.; Vandergrift, Gregory W.; Cheng, Zezhen; China, Swarup; Zelenyuk, Alla; Shilling, John E.

doi:10.1021/acs.est.3c03532

Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol

Journal Article · Thu Sep 14 00:00:00 EDT 2023 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.3c03532· OSTI ID:2203048

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Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Recent studies have shown that instantaneous gas-particle equilibrium partitioning assumptions fail to predict SOA formation, even at high relative humidity (~85%), and photochemical aging seems to be one driving factor. In this study, we probe the minimum aging time scale required to observe nonequilibrium partitioning of semivolatile organic compounds (SVOCs) between the gas and aerosol phase at ~50% RH. Seed isoprene SOA is generated by photo-oxidation in the presence of effloresced ammonium sulfate seeds at <1 ppbv NO_x, aged photochemically or in the dark for 0.3–6 h, and subsequently exposed to fresh isoprene SVOCs. Our results show that the equilibrium partitioning assumption is accurate for fresh isoprene SOA but breaks down after isoprene SOA has been aged for as short as 20 min even in the dark. Modeling results show that a semisolid SOA phase state is necessary to reproduce the observed particle size distribution evolution. The observed nonequilibrium partitioning behavior and inferred semisolid phase state are corroborated by offline mass spectrometric analysis on the bulk aerosol particles showing the formation of organosulfates and oligomers. Here, the unexpected short time scale for the phase transition within isoprene SOA has important implications for the growth of atmospheric ultrafine particles to climate-relevant sizes.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). ARM Data Center

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Contributing Organization:: Pacific Northwest National Laboratory (PNNL); Brookhaven National Laboratory (BNL); Argonne National Laboratory (ANL); Oak Ridge National Laboratory (ORNL)

Grant/Contract Number:: AC06-76RL01830; AC05-76RL01830

OSTI ID:: 2203048

Alternate ID(s):: OSTI ID: 2203049

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 38 Vol. 57; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (96)

Global observations of aerosol-cloud-precipitation-climate interactions: Aerosol-cloud-climate interactions Rosenfeld, Daniel; Andreae, Meinrat O.; Asmi, Ari Reviews of Geophysics, Vol. 52, Issue 4 https://doi.org/10.1002/2013rg000441	journal	November 2014
Physical properties of ambient and laboratory-generated secondary organic aerosol: PHYSICAL PROPERTIES OF ORGANIC AEROSOL O'Brien, Rachel E.; Neu, Alexander; Epstein, Scott A. Geophysical Research Letters, Vol. 41, Issue 12 https://doi.org/10.1002/2014GL060219	journal	June 2014
Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol Shrivastava, Manish; Cappa, Christopher D.; Fan, Jiwen Reviews of Geophysics, Vol. 55, Issue 2 https://doi.org/10.1002/2016RG000540	journal	June 2017
Chemical and microphysical characterization of ambient aerosols with the aerodyne aerosol mass spectrometer Canagaratna, M. R.; Jayne, J. T.; Jimenez, J. L. Mass Spectrometry Reviews, Vol. 26, Issue 2 https://doi.org/10.1002/mas.20115	journal	January 2007
Understanding atmospheric organic aerosols via factor analysis of aerosol mass spectrometry: a review Zhang, Qi; Jimenez, Jose L.; Canagaratna, Manjula R. Analytical and Bioanalytical Chemistry, Vol. 401, Issue 10 https://doi.org/10.1007/s00216-011-5355-y	journal	October 2011
Second-generation inorganic aerosol model Wexler, Anthony S.; Seinfeld, John H. Atmospheric Environment. Part A. General Topics, Vol. 25, Issue 12 https://doi.org/10.1016/0960-1686(91)90203-J	journal	January 1991
An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol Pankow, James F. Atmospheric Environment, Vol. 28, Issue 2 https://doi.org/10.1016/1352-2310(94)90094-9	journal	January 1994
Measuring and simulating particulate organics in the atmosphere: problems and prospects Turpin, Barbara J.; Saxena, Pradeep; Andrews, Elisabeth Atmospheric Environment, Vol. 34, Issue 18 https://doi.org/10.1016/S1352-2310(99)00501-4	journal	January 2000
Biogenic volatile organic compound emissions from desert vegetation of the southwestern US Geron, Chris; Guenther, Alex; Greenberg, Jim Atmospheric Environment, Vol. 40, Issue 9 https://doi.org/10.1016/j.atmosenv.2005.11.011	journal	March 2006
Multiphase reactivity of gaseous hydroperoxide oligomers produced from isoprene ozonolysis in the presence of acidified aerosols Riva, Matthieu; Budisulistiorini, Sri Hapsari; Zhang, Zhenfa Atmospheric Environment, Vol. 152 https://doi.org/10.1016/j.atmosenv.2016.12.040	journal	March 2017
Source apportionment of submicron organic aerosol collected from Atlanta, Georgia, during 2014–2015 using the aerosol chemical speciation monitor (ACSM) Rattanavaraha, Weruka; Canagaratna, Manjula R.; Budisulistiorini, Sri Hapsari Atmospheric Environment, Vol. 167 https://doi.org/10.1016/j.atmosenv.2017.07.055	journal	October 2017
Efficient Isoprene Secondary Organic Aerosol Formation from a Non-IEPOX Pathway Liu, Jiumeng; D’Ambro, Emma L.; Lee, Ben H. Environmental Science & Technology, Vol. 50, Issue 18 https://doi.org/10.1021/acs.est.6b01872	journal	September 2016
Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides Riva, Matthieu; Budisulistiorini, Sri H.; Chen, Yuzhi Environmental Science & Technology, Vol. 50, Issue 18 https://doi.org/10.1021/acs.est.6b02511	journal	September 2016
Isomerization of Second-Generation Isoprene Peroxy Radicals: Epoxide Formation and Implications for Secondary Organic Aerosol Yields D’Ambro, Emma L.; Møller, Kristian H.; Lopez-Hilfiker, Felipe D. Environmental Science & Technology, Vol. 51, Issue 9 https://doi.org/10.1021/acs.est.7b00460	journal	April 2017
Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol Zaveri, Rahul A.; Shilling, John E.; Zelenyuk, Alla Environmental Science & Technology, Vol. 52, Issue 3 https://doi.org/10.1021/acs.est.7b04623	journal	January 2018
Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties Riva, Matthieu; Chen, Yuzhi; Zhang, Yue Environmental Science & Technology, Vol. 53, Issue 15 https://doi.org/10.1021/acs.est.9b01019	journal	June 2019
The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Zhang, Yue; Nichman, Leonid; Spencer, Peyton Environmental Science & Technology, Vol. 53, Issue 21 https://doi.org/10.1021/acs.est.9b03317	journal	September 2019
Kinetics and Condensed-Phase Products in Multiphase Ozonolysis of an Unsaturated Triglyceride Zhou, Zilin; Zhou, Shouming; Abbatt, Jonathan P. D. Environmental Science & Technology, Vol. 53, Issue 21 https://doi.org/10.1021/acs.est.9b04460	journal	October 2019
Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol Zaveri, Rahul A.; Shilling, John E.; Zelenyuk, Alla Environmental Science & Technology, Vol. 54, Issue 5 https://doi.org/10.1021/acs.est.9b05514	journal	January 2020
Photolysis Controls Atmospheric Budgets of Biogenic Secondary Organic Aerosol Zawadowicz, Maria A.; Lee, Ben H.; Shrivastava, Manish Environmental Science & Technology, Vol. 54, Issue 7 https://doi.org/10.1021/acs.est.9b07051	journal	March 2020
Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Chen, Yuzhi; Zhang, Yue; Lambe, Andrew T. Environmental Science & Technology Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.estlett.0c00276	journal	May 2020
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX) Zhang, Yue; Chen, Yuzhi; Lambe, Andrew T. Environmental Science & Technology Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acs.estlett.8b00044	journal	February 2018
Volatility and Viscosity Are Correlated in Terpene Secondary Organic Aerosol Formed in a Flow Reactor Champion, Wyatt M.; Rothfuss, Nicholas E.; Petters, Markus D. Environmental Science & Technology Letters, Vol. 6, Issue 9 https://doi.org/10.1021/acs.estlett.9b00412	journal	August 2019
Molecular Characterization of Organosulfate-Dominated Aerosols over Agricultural Fields from the Southern Great Plains by High-Resolution Mass Spectrometry Vandergrift, Gregory W.; Shawon, Abu Sayeed Md; Dexheimer, Darielle N. ACS Earth and Space Chemistry, Vol. 6, Issue 7 https://doi.org/10.1021/acsearthspacechem.2c00043	journal	May 2022
Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Zhang, Yue; Chen, Yuzhi; Lei, Ziying ACS Earth and Space Chemistry, Vol. 3, Issue 12 https://doi.org/10.1021/acsearthspacechem.9b00209	journal	October 2019
Photochemical Aging Alters Secondary Organic Aerosol Partitioning Behavior Shilling, John E.; Zawadowicz, Maria A.; Liu, Jiumeng ACS Earth and Space Chemistry, Vol. 3, Issue 12 https://doi.org/10.1021/acsearthspacechem.9b00248	journal	October 2019
Phase Transitions of Aqueous Atmospheric Particles Martin, Scot T. Chemical Reviews, Vol. 100, Issue 9 https://doi.org/10.1021/cr990034t	journal	September 2000
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics Donahue, N. M.; Robinson, A. L.; Stanier, C. O. Environmental Science & Technology, Vol. 40, Issue 8 https://doi.org/10.1021/es052297c	journal	April 2006
Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds Lin, Ying-Hsuan; Zhang, Zhenfa; Docherty, Kenneth S. Environmental Science & Technology, Vol. 46, Issue 1 https://doi.org/10.1021/es202554c	journal	November 2011
On the Mixing and Evaporation of Secondary Organic Aerosol Components Loza, Christine L.; Coggon, Matthew M.; Nguyen, Tran B. Environmental Science & Technology, Vol. 47, Issue 12 https://doi.org/10.1021/es400979k	journal	May 2013
Light-Absorbing Oligomer Formation in Secondary Organic Aerosol from Reactive Uptake of Isoprene Epoxydiols Lin, Ying-Hsuan; Budisulistiorini, Sri Hapsari; Chu, Kevin Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es503142b	journal	October 2014
Reactive Uptake of an Isoprene-Derived Epoxydiol to Submicron Aerosol Particles Gaston, Cassandra J.; Riedel, Theran P.; Zhang, Zhenfa Environmental Science & Technology, Vol. 48, Issue 19 https://doi.org/10.1021/es5034266	journal	September 2014
Evaporation Kinetics of Laboratory-Generated Secondary Organic Aerosols at Elevated Relative Humidity Wilson, Jacqueline; Imre, Dan; Beránek, Josef Environmental Science & Technology, Vol. 49, Issue 1 https://doi.org/10.1021/es505331d	journal	December 2014
Gas/Particle Partitioning and Secondary Organic Aerosol Yields Odum, Jay R.; Hoffmann, Thorsten; Bowman, Frank Environmental Science & Technology, Vol. 30, Issue 8 https://doi.org/10.1021/es950943+	journal	July 1996
Heterogeneous Reactions of Isoprene-Derived Epoxides: Reaction Probabilities and Molar Secondary Organic Aerosol Yield Estimates Riedel, Theran P.; Lin, Ying-Hsuan; Budisulistiorini, Sri Hapsari Environmental Science & Technology Letters, Vol. 2, Issue 2 https://doi.org/10.1021/ez500406f	journal	January 2015
Viscosity behavior of associated liquids at lower temperatures and vapor pressures Thomas, Leo H.; Meatyard, Robert; Smith, Harry Journal of Chemical & Engineering Data, Vol. 24, Issue 3 https://doi.org/10.1021/je60082a011	journal	July 1979
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H. The Journal of Physical Chemistry A, Vol. 110, Issue 31 https://doi.org/10.1021/jp061734m	journal	August 2006
Hygroscopic Influence on the Semisolid-to-Liquid Transition of Secondary Organic Materials Bateman, Adam P.; Bertram, Allan K.; Martin, Scot T. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp508521c	journal	November 2014
Reactivity of Liquid and Semisolid Secondary Organic Carbon with Chloride and Nitrate in Atmospheric Aerosols Wang, Bingbing; O’Brien, Rachel E.; Kelly, Stephen T. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp510336q	journal	November 2014
Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) Zaveri, Rahul A.; Easter, Richard C.; Fast, Jerome D. Journal of Geophysical Research, Vol. 113, Issue D13 https://doi.org/10.1029/2007JD008782	journal	January 2008
Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes: UBIQUITY AND DOMINANCE OF OXYGENATED OA Zhang, Q.; Jimenez, J. L.; Canagaratna, M. R. Geophysical Research Letters, Vol. 34, Issue 13 https://doi.org/10.1029/2007gl029979	journal	July 2007
Equilibration timescale of atmospheric secondary organic aerosol partitioning Shiraiwa, Manabu; Seinfeld, John H. Geophysical Research Letters, Vol. 39, Issue 24 https://doi.org/10.1029/2012GL054008	journal	December 2012
Temperature- and Humidity-Dependent Phase States of Secondary Organic Aerosols Petters, Sarah S.; Kreidenweis, Sonia M.; Grieshop, Andrew P. Geophysical Research Letters, Vol. 46, Issue 2 https://doi.org/10.1029/2018GL080563	journal	January 2019
An amorphous solid state of biogenic secondary organic aerosol particles Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas Nature, Vol. 467, Issue 7317 https://doi.org/10.1038/nature09455	journal	October 2010
A large source of low-volatility secondary organic aerosol Ehn, Mikael; Thornton, Joel A.; Kleist, Einhard Nature, Vol. 506, Issue 7489 https://doi.org/10.1038/nature13032	journal	February 2014
The role of low-volatility organic compounds in initial particle growth in the atmosphere Tröstl, Jasmin; Chuang, Wayne K.; Gordon, Hamish Nature, Vol. 533, Issue 7604 https://doi.org/10.1038/nature18271	journal	May 2016
Global distribution of particle phase state in atmospheric secondary organic aerosols Shiraiwa, Manabu; Li, Ying; Tsimpidi, Alexandra P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15002	journal	April 2017
The contribution of organics to atmospheric nanoparticle growth Riipinen, Ilona; Yli-Juuti, Taina; Pierce, Jeffrey R. Nature Geoscience, Vol. 5, Issue 7 https://doi.org/10.1038/ngeo1499	journal	June 2012
Collocated observations of cloud condensation nuclei, particle size distributions, and chemical composition Schmale, Julia; Henning, Silvia; Henzing, Bas Scientific Data, Vol. 4, Issue 1 https://doi.org/10.1038/sdata.2017.3	journal	March 2017
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere Koop, Thomas; Bookhold, Johannes; Shiraiwa, Manabu Physical Chemistry Chemical Physics, Vol. 13, Issue 43 https://doi.org/10.1039/c1cp22617g	journal	January 2011
Gas–particle partitioning of atmospheric aerosols: interplay of physical state, non-ideal mixing and morphology Shiraiwa, Manabu; Zuend, Andreas; Bertram, Allan K. Physical Chemistry Chemical Physics, Vol. 15, Issue 27 https://doi.org/10.1039/c3cp51595h	journal	January 2013
The transition from liquid to solid-like behaviour in ultrahigh viscosity aerosol particles Power, R. M.; Simpson, S. H.; Reid, J. P. Chemical Science, Vol. 4, Issue 6 https://doi.org/10.1039/c3sc50682g	journal	January 2013
Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol Cui, Tianqu; Zeng, Zhexi; dos Santos, Erickson O. Environmental Science: Processes & Impacts, Vol. 20, Issue 11 https://doi.org/10.1039/c8em00308d	journal	January 2018
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Morphology of mixed primary and secondary organic particles and the adsorption of spectator organic gases during aerosol formation Vaden, T. D.; Song, C.; Zaveri, R. A. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911206107	journal	March 2010
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol Vaden, T. D.; Imre, D.; Beranek, J. Proceedings of the National Academy of Sciences, Vol. 108, Issue 6 https://doi.org/10.1073/pnas.1013391108	journal	January 2011
Gas uptake and chemical aging of semisolid organic aerosol particles Shiraiwa, M.; Ammann, M.; Koop, T. Proceedings of the National Academy of Sciences, Vol. 108, Issue 27 https://doi.org/10.1073/pnas.1103045108	journal	June 2011
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P. Proceedings of the National Academy of Sciences, Vol. 110, Issue 20 https://doi.org/10.1073/pnas.1219548110	journal	April 2013
Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications Jokinen, Tuija; Berndt, Torsten; Makkonen, Risto Proceedings of the National Academy of Sciences, Vol. 112, Issue 23 https://doi.org/10.1073/pnas.1423977112	journal	May 2015
Improving our fundamental understanding of the role of aerosol−cloud interactions in the climate system Seinfeld, John H.; Bretherton, Christopher; Carslaw, Kenneth S. Proceedings of the National Academy of Sciences, Vol. 113, Issue 21 https://doi.org/10.1073/pnas.1514043113	journal	May 2016
Lability of secondary organic particulate matter Liu, Pengfei; Li, Yong Jie; Wang, Yan Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1603138113	journal	October 2016
Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts Baboomian, Vahe J.; Crescenzo, Giuseppe V.; Huang, Yuanzhou Proceedings of the National Academy of Sciences, Vol. 119, Issue 43 https://doi.org/10.1073/pnas.2208121119	journal	October 2022
Diffusion-Limited Versus Quasi-Equilibrium Aerosol Growth Zhang, Xi; Pandis, Spyros N.; Seinfeld, John H. Aerosol Science and Technology, Vol. 46, Issue 8 https://doi.org/10.1080/02786826.2012.679344	journal	August 2012
Hydrolysis of Organonitrate Functional Groups in Aerosol Particles Liu, Shang; Shilling, John E.; Song, Chen Aerosol Science and Technology, Vol. 46, Issue 12 https://doi.org/10.1080/02786826.2012.716175	journal	December 2012
Phase State and Deliquescence Hysteresis of Ammonium-Sulfate-Seeded Secondary Organic Aerosol Saukko, Erkka; Zorn, Soeren; Kuwata, Mikinori Aerosol Science and Technology, Vol. 49, Issue 7 https://doi.org/10.1080/02786826.2015.1050085	journal	May 2015
Coalescence-based assessment of aerosol phase state using dimers prepared through a dual-differential mobility analyzer technique Rothfuss, Nicholas E.; Petters, Markus D. Aerosol Science and Technology, Vol. 50, Issue 12 https://doi.org/10.1080/02786826.2016.1221050	journal	August 2016
Aerosols in atmospheric chemistry and biogeochemical cycles of nutrients Kanakidou, Maria; Myriokefalitakis, Stelios; Tsigaridis, Kostas Environmental Research Letters, Vol. 13, Issue 6 https://doi.org/10.1088/1748-9326/aabcdb	journal	May 2018
Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest Zaveri, Rahul A.; Wang, Jian; Fan, Jiwen Science Advances, Vol. 8, Issue 2 https://doi.org/10.1126/sciadv.abj0329	journal	January 2022
Aerosols, Climate, and the Hydrological Cycle Ramanathan, V. Science, Vol. 294, Issue 5549 https://doi.org/10.1126/science.1064034	journal	December 2001
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
Aerosol Impacts on Climate and Biogeochemistry Mahowald, Natalie; Ward, Daniel S.; Kloster, Silvia Annual Review of Environment and Resources, Vol. 36, Issue 1 https://doi.org/10.1146/annurev-environ-042009-094507	journal	November 2011
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations Riipinen, I.; Pierce, J. R.; Yli-Juuti, T. Atmospheric Chemistry and Physics, Vol. 11, Issue 8 https://doi.org/10.5194/acp-11-3865-2011	journal	January 2011
Humidity-dependent phase state of SOA particles from biogenic and anthropogenic precursors Saukko, E.; Lambe, A. T.; Massoli, P. Atmospheric Chemistry and Physics, Vol. 12, Issue 16 https://doi.org/10.5194/acp-12-7517-2012	journal	January 2012
Deliquescence, efflorescence, and phase miscibility of mixed particles of ammonium sulfate and isoprene-derived secondary organic material Smith, M. L.; Bertram, A. K.; Martin, S. T. Atmospheric Chemistry and Physics, Vol. 12, Issue 20 https://doi.org/10.5194/acp-12-9613-2012	journal	January 2012
The AeroCom evaluation and intercomparison of organic aerosol in global models Tsigaridis, K.; Daskalakis, N.; Kanakidou, M. Atmospheric Chemistry and Physics, Vol. 14, Issue 19 https://doi.org/10.5194/acp-14-10845-2014	journal	January 2014
Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds Nguyen, T. B.; Coggon, M. M.; Bates, K. H. Atmospheric Chemistry and Physics, Vol. 14, Issue 7 https://doi.org/10.5194/acp-14-3497-2014	journal	January 2014
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction Zaveri, R. A.; Easter, R. C.; Shilling, J. E. Atmospheric Chemistry and Physics, Vol. 14, Issue 10 https://doi.org/10.5194/acp-14-5153-2014	journal	January 2014
Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements Hu, W. W.; Campuzano-Jost, P.; Palm, B. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 20 https://doi.org/10.5194/acp-15-11807-2015	journal	January 2015
Impact of gas-to-particle partitioning approaches on the simulated radiative effects of biogenic secondary organic aerosol Scott, C. E.; Spracklen, D. V.; Pierce, J. R. Atmospheric Chemistry and Physics, Vol. 15, Issue 22 https://doi.org/10.5194/acp-15-12989-2015	journal	January 2015
Relative humidity-dependent viscosities of isoprene-derived secondary organic material and atmospheric implications for isoprene-dominant forests Song, M.; Liu, P. F.; Hanna, S. J. Atmospheric Chemistry and Physics, Vol. 15, Issue 9 https://doi.org/10.5194/acp-15-5145-2015	journal	January 2015
Changing shapes and implied viscosities of suspended submicron particles Zhang, Y.; Sanchez, M. S.; Douet, C. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-7819-2015	journal	January 2015
Hydroxyl radicals from secondary organic aerosol decomposition in water Tong, Haijie; Arangio, Andrea M.; Lakey, Pascale S. J. Atmospheric Chemistry and Physics, Vol. 16, Issue 3 https://doi.org/10.5194/acp-16-1761-2016	journal	January 2016
Observation of viscosity transition in α -pinene secondary organic aerosol Järvinen, Emma; Ignatius, Karoliina; Nichman, Leonid Atmospheric Chemistry and Physics, Vol. 16, Issue 7 https://doi.org/10.5194/acp-16-4423-2016	journal	January 2016
Seasonal characterization of submicron aerosol chemical composition and organic aerosol sources in the southeastern United States: Atlanta, Georgia,and Look Rock, Tennessee Budisulistiorini, Sri Hapsari; Baumann, Karsten; Edgerton, Eric S. Atmospheric Chemistry and Physics, Vol. 16, Issue 8 https://doi.org/10.5194/acp-16-5171-2016	journal	January 2016
Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NO _x conditions D'Ambro, Emma L.; Lee, Ben H.; Liu, Jiumeng Atmospheric Chemistry and Physics, Vol. 17, Issue 1 https://doi.org/10.5194/acp-17-159-2017	journal	January 2017
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition DeRieux, Wing-Sy Wong; Li, Ying; Lin, Peng Atmospheric Chemistry and Physics, Vol. 18, Issue 9 https://doi.org/10.5194/acp-18-6331-2018	journal	January 2018
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M. Atmospheric Chemistry and Physics, Vol. 19, Issue 3 https://doi.org/10.5194/acp-19-1491-2019	journal	January 2019
A predictive group-contribution model for the viscosity of aqueous organic aerosol Gervasi, Natalie R.; Topping, David O.; Zuend, Andreas Atmospheric Chemistry and Physics, Vol. 20, Issue 5 https://doi.org/10.5194/acp-20-2987-2020	journal	January 2020
Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Li, Ying; Day, Douglas A.; Stark, Harald Atmospheric Chemistry and Physics, Vol. 20, Issue 13 https://doi.org/10.5194/acp-20-8103-2020	journal	January 2020
Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model Schmedding, Ryan; Rasool, Quazi Z.; Zhang, Yue Atmospheric Chemistry and Physics, Vol. 20, Issue 13 https://doi.org/10.5194/acp-20-8201-2020	journal	January 2020
Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and α-pinene Galeazzo, Tommaso; Valorso, Richard; Li, Ying Atmospheric Chemistry and Physics, Vol. 21, Issue 13 https://doi.org/10.5194/acp-21-10199-2021	journal	July 2021
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Amorphous and crystalline aerosol particles interacting with water vapor: conceptual framework and experimental evidence for restructuring, phase transitions and kinetic limitations Mikhailov, E.; Vlasenko, S.; Martin, S. T. Atmospheric Chemistry and Physics, Vol. 9, Issue 24 https://doi.org/10.5194/acp-9-9491-2009	journal	January 2009
Reviews and syntheses: Use and misuse of peak intensities from high resolution mass spectrometry in organic matter studies: opportunities for robust usage Kew, William; Myers-Pigg, Allison; Chang, Christine https://doi.org/10.5194/egusphere-2022-1105	preprint	October 2022
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012
Hygroscopic Behavior of Ammonium Sulfate, Ammonium Nitrate, and their Mixture Particles Wu, Li; Li, Xue; Ro, Chul-Un Asian Journal of Atmospheric Environment, Vol. 13, Issue 3 https://doi.org/10.5572/ajae.2019.13.3.196	journal	September 2019

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Journal Article · Thu Dec 14 23:00:00 EST 2017 · Environmental Science and Technology · OSTI ID:1421345

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54 ENVIRONMENTAL SCIENCES
aerosols
diffusion limitations
equilibrium
equilibrium partitioning
isoprene
nanoparticles
phase transitions
physiology
secondary organic aerosol (SOA)

Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol

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