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Title: Sonochemical synthesis of luminescent CeCO{sub 3}OH one-dimensional quadrangular prisms

Journal Article · · Materials Research Bulletin
 [1];  [1];  [2]
  1. New Materials and Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Zhengzhou Road 53, Qingdao 266042 (China)
  2. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042 (China)

Orthorhombic single-crystalline cerium carbonate hydroxide (CeCO{sub 3}OH) with one-dimensional (1D) microstructures has been successfully synthesized by a facile sonochemical reaction between cerous nitrate and urea. These 1D microstructures were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM). The as-synthesized CeCO{sub 3}OH has uniform lengths and good dispersion. Synthetic parameters, such as the concentration of reagents, were found to have close relationship with the morphologies and sizes of the final products. The ultrasound-induced oriented attachment growth mechanism has been proposed for the possible formation mechanism of sample. Room-temperature photoluminescence of CeCO{sub 3}OH samples with different morphologies has also been investigated.

OSTI ID:
22029748
Journal Information:
Materials Research Bulletin, Vol. 44, Issue 10; Other Information: Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English