NaCu(Ta{sub 1-y}Nb{sub y}){sub 4}O{sub 11} solid solution: A tunable band gap spanning the visible-light wavelengths
- Department of Chemistry, North Carolina State University, Raleigh, NC 27695 (United States)
The new solid-solution NaCu(Ta{sub 1-y}Nb{sub y}){sub 4}O{sub 11} (0{<=}y{<=}0.7) was synthesized by solid-state methods in the form of bulk powders that ranged from light-yellow to brown colored and were characterized by powder X-ray diffraction techniques (Space group R-3c (no. 167); Z=6; a=6.214(1)-6.218(1) Angstrom-Sign and c=36.86(1)-36.94(1) Angstrom-Sign ). Full-profile Rietveld refinements confirmed a site-differentiated ordering of the Cu(I) and Na cations, i.e., occupying the 12c (linear environment) and 18d (seven-coordinate environment) crystallographic sites respectively. Conversely, a statistical mixture of Ta(V) and Nb(V) cations occurred over the 6b (octahedral environment) or the 18e (pentagonal-bipyramidal environment) crystallographic sites, without any preferential segregation. The UV-Vis diffuse reflectance spectra showed a significant red-shift of the optical bandgap size (indirect) from {approx}2.70 eV to {approx}1.80 eV across the solid solution with increasing Nb(V) content. Electronic-structure calculations using the tight-binding linear-muffin-tin-orbital approach showed that the reduction in bandgap size arises from the introduction of the lower-energy Nb 4d{sup 0} orbitals into the conduction band and consequently a lower energy of the conduction band edge. The lowest-energy bandgap transitions were found to be derived from electronic transitions between the filled Cu(I) and the empty Nb(V) d-orbitals, with a small amount of mixing with the O 2p orbitals. The resulting conduction and valence band energies are found to approximately bracket the redox potentials for water reduction and oxidation, and meeting the thermodynamic requirements for photocatalytic water-splitting reactions. - Graphical Abstract: The NaCu(Ta{sub 1-y}Nb{sub y}){sub 4}O{sub 11} (0{<=}y{<=}0.7) solid solution shows a statistical occupancy of the Ta(V) and Nb(V) cations in both octahedral and pentagonal bipyramidal environments. An increasing Nb(V) content also causes a significant red-shift of the bandgap size from {approx}2.70 eV to {approx}1.80 eV. Highlights: Black-Right-Pointing-Pointer Double solid-solution of M(I) (=Cu, Na) and M(V) (=Nb, Ta) crystallographic sites. Black-Right-Pointing-Pointer Increasing Nb content leads to tunable bandgap size from {approx}2.70 eV to {approx}1.80 eV across the solid solution. Black-Right-Pointing-Pointer Layers of MO{sub 7} (M=Ta, Nb) pentagonal bipyramids and isolated MO{sub 6} octahedra.
- OSTI ID:
- 22012201
- Journal Information:
- Journal of Solid State Chemistry, Vol. . 191; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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