ROVIBRATIONALLY RESOLVED DIRECT PHOTODISSOCIATION THROUGH THE LYMAN AND WERNER TRANSITIONS OF H{sub 2} FOR FUV/X-RAY-IRRADIATED ENVIRONMENTS

Journal Article · Fri Feb 10 04:00:00 EST 2012 · Astrophysical Journal

DOI:https://doi.org/10.1088/0004-637X/746/1/78· OSTI ID:22011800

Gay, C D; Porter, R L; Stancil, P C ^[1]; Abel, N P ^[2]; Ferland, G J ^[3]; Shaw, G ^[4]; Williams, R J. R., ^[5]

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1. Department of Physics and Astronomy and Center for Simulational Physics, University of Georgia, Athens, GA 30602-2451 (United States)
2. Math, Computers, Geology, and Physics Department, University of Cincinnati, Clermont Campus, Batavia, OH 45103 (United States)
3. Department of Physics and Astronomy, University of Kentucky, Lexington, KY (United States)
4. Centre for Excellence in Basic Sciences, UM-DAE, Vidhyanagari Campus, Mumbai-400098 (India)
5. AWE plc, Aldermaston, Reading RG7 4PR (United Kingdom)

Using ab initio potential curves and dipole transition moments, cross-section calculations were performed for the direct continuum photodissociation of H{sub 2} through the B{sup 1}{Sigma}{sup +}{sub u} <- X{sup 1}{Sigma}{sup +}{sub g} (Lyman) and C{sup 1}{Pi}{sub u} <- X{sup 1}{Sigma}{sup +}{sub g} (Werner) transitions. Partial cross-sections were obtained for wavelengths from 100 A to the dissociation threshold between the upper electronic state and each of the 301 bound rovibrational levels v''J'' within the ground electronic state. The resulting cross-sections are incorporated into three representative classes of interstellar gas models: diffuse clouds, photon-dominated regions, and X-ray-dominated regions (XDRs). The models, which used the CLOUDY plasma/molecular spectra simulation code, demonstrate that direct photodissociation is comparable to fluorescent dissociation (or spontaneous radiative dissociation, the Solomon process) as an H{sub 2} destruction mechanism in intense far-ultraviolet or X-ray-irradiated gas. In particular, changes in H{sub 2} rotational column densities are found to be as large as 20% in the XDR model with the inclusion of direct photodissociation. The photodestruction rate from some high-lying rovibrational levels can be enhanced by pumping from H Ly{beta} due to a wavelength coincidence with cross-section resonances resulting from quasi-bound levels of the upper electronic states. Given the relatively large size of the photodissociation data set, a strategy is described to create truncated, but reliable, cross-section data consistent with the wavelength resolving power of typical observations.

• OSTI ID: 22011800
• Journal Information: Astrophysical Journal, Journal Name: Astrophysical Journal Journal Issue: 1 Vol. 746; ISSN ASJOAB; ISSN 0004-637X
• Country of Publication: United States
• Language: English

Related Subjects

79 ASTRONOMY AND ASTROPHYSICS
ASTROPHYSICS
FAR ULTRAVIOLET RADIATION
HYDROGEN
PHOTOLYSIS
X RADIATION