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Title: A SEARCH FOR INTERSTELLAR CARBON-CHAIN ALCOHOL HC{sub 4}OH IN STAR-FORMING REGION L1527 AND DARK CLOUD TMC-1

Journal Article · · Astrophysical Journal
; ; ;  [1];  [2]; ;  [3]; ;  [4]
  1. Department of Chemistry, Faculty of Science Division I, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku 162-8601, Tokyo (Japan)
  2. Nobeyama Radio Observatory, 462-2 Nobeyama, Minamimaki, Minamisaku, Nagano 384-1305 (Japan)
  3. Department of Chemistry, Faculty of Science, Shizuoka University, 836 Oya, Suruga-ku, Shizuoka 422-8529 (Japan)
  4. Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University, 7-1 Kioi-cho, Chiyoda-ku 102-8554, Tokyo (Japan)

We report a sensitive search for the rotational transitions of the carbon-chain alcohol HC{sub 4}OH in the frequency range 21.2-46.7 GHz in the star-forming region L1527 and the dark cloud TMC-1. The motivation was laboratory detection of HC{sub 4}OH by microwave spectroscopy. Despite achieving rms noise levels of several millikelvin in the antenna temperature using the 45 m telescope at Nobeyama Radio Observatory, the detection was not successful, leading to 3{sigma} upper limits corresponding to the column densities of 2.0 Multiplication-Sign 10{sup 12} and 5.6 Multiplication-Sign 10{sup 12} cm{sup -2} in L1527 and TMC-1, respectively. These upper limits indicate that [HC{sub 4}OH]/[HC{sub 5}N] ratios are less than 0.3 and 0.1 in L1527 and TMC-1, respectively, where HC{sub 5}N is an HC{sub 4}-chain cyanide and HC{sub 4}OH is a hydroxide. These ratios suggest that the cyano carbon-chain molecule dominates the hydroxyl carbon-chain molecule in L1527 and TMC-1. This is contrary to the case of saturated compounds in hot cores, e.g., CH{sub 3}OH and CH{sub 3}CN, and can be a chemical feature of carbon-chain molecules in L1527 and TMC-1. In addition, the column densities of the 'unsubstituted' carbon-chain molecule C{sub 4}H and the sulfur-bearing molecules SO and HCS{sup +} were determined from detected lines in L1527.

OSTI ID:
22004217
Journal Information:
Astrophysical Journal, Vol. 744, Issue 2; Other Information: Country of input: International Atomic Energy Agency (IAEA); ISSN 0004-637X
Country of Publication:
United States
Language:
English