[La(UO{sub 2})V{sub 2}O{sub 7}][(UO{sub 2})(VO{sub 4})] the first lanthanum uranyl-vanadate with structure built from two types of sheets based upon the uranophane anion-topology

Journal Article · Sun Jan 15 00:00:00 EST 2012 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2011.10.042· OSTI ID:21612869

Mer, A; Obbade, S; Rivenet, M ^[1]; Renard, C ^[1]; Abraham, F ^[1]

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1. Univ. Lille Nord de France, Unite de Catalyse et de Chimie du Solide, UCCS UMR CNRS 8181, ENSCL-USTL, B.P. 90108, 59652 Villeneuve d'Ascq Cedex (France)

The new lanthanum uranyl vanadate divanadate, [La(UO{sub 2})V{sub 2}O{sub 7}][(UO{sub 2})(VO{sub 4})] was obtained by reaction at 800 Degree-Sign C between lanthanum chloride, uranium oxide (U{sub 3}O{sub 8}) and vanadium oxide (V{sub 2}O{sub 5}) and the structure was determined from single-crystal X-ray diffraction data. This compound crystallizes in the orthorhombic system with space group P2{sub 1}2{sub 1}2{sub 1} and unit-cell parameters a=6.9470(2) A, b=7.0934(2) A, c=25.7464(6) A, V=1268.73(5) A{sup 3}, Z=4. A full matrix least-squares refinement yielded R{sub 1}=0.0219 for 5493 independent reflections. The crystal structure is characterized by the stacking of uranophane-type sheets {sup 2}{sub {infinity}}[(UO{sub 2})(VO{sub 4})]{sup -} and double layers {sup 2}{sub {infinity}}[La(UO{sub 2})(V{sub 2}O{sub 7})]{sup +} connected through La-O bonds involving the uranyl oxygen of the uranyl-vanadate sheets. The double layers result from the connection of two {sup 2}{sub {infinity}}[La(UO{sub 2})(VO{sub 4}){sub 2}]{sup -} sheets derived from the uranophane anion-topology by replacing half of the uranyl ions by lanthanum atoms and connected through the formation of divanadate entities. - Graphical abstract: A view of the three-dimensional structure of [La(UO{sub 2})V{sub 2}O{sub 7}][(UO{sub 2})(VO{sub 4})]. Highlights: Black-Right-Pointing-Pointer New lanthanum uranyl vanadate divanadate has been synthesized. Black-Right-Pointing-Pointer Structure was determined from single-crystal X-ray diffraction data. Black-Right-Pointing-Pointer Structure is characterized by uranophane-type sheets and double layers {sup 2}{sub {infinity}}[La(UO{sub 2})(V{sub 2}O{sub 7})]{sup +}.

• OSTI ID: 21612869
• Journal Information: Journal of Solid State Chemistry, Vol. 185; Other Information: DOI: 10.1016/j.jssc.2011.10.042; PII: S0022-4596(11)00584-6; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ANIONS
LANTHANUM
LANTHANUM CHLORIDES
LAYERS
LEAST SQUARE FIT
MONOCRYSTALS
ORTHORHOMBIC LATTICES
SHEETS
SOLIDS
SPACE GROUPS
SYNTHESIS
TOPOLOGY
URANIUM DIOXIDE
URANIUM OXIDES U3O8
URANOPHANE
VANADATES
VANADIUM OXIDES
X-RAY DIFFRACTION
ACTINIDE COMPOUNDS
CHALCOGENIDES
CHARGED PARTICLES
CHLORIDES
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
CRYSTALS
DIFFRACTION
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
IONS
LANTHANUM COMPOUNDS
LANTHANUM HALIDES
MATERIALS
MATHEMATICAL SOLUTIONS
MATHEMATICS
MAXIMUM-LIKELIHOOD FIT
METALS
MINERALS
NUMERICAL SOLUTION
OXIDES
OXYGEN COMPOUNDS
RADIOACTIVE MATERIALS
RADIOACTIVE MINERALS
RARE EARTH COMPOUNDS
RARE EARTHS
SCATTERING
SILICATE MINERALS
SYMMETRY GROUPS
TRANSITION ELEMENT COMPOUNDS
URANIUM COMPOUNDS
URANIUM MINERALS
URANIUM OXIDES
VANADIUM COMPOUNDS