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Title: Novel organic polymer-inorganic hybrid material zinc poly(styrene-phenylvinylphosphonate)-phosphate prepared with a simple method

Abstract

A novel type of organic polymer-inorganic hybrid material layered crystalline zinc poly(styrene-phenylvinylphosphonate)-phosphate (ZnPS-PVPP) was synthesized under mild conditions in the absence of any template. And the ZnPS-PVPP were characterized by FT-IR, diffusion reflection UV-vis, AAS, N{sub 2} volumetric adsorption, SEM, TEM and TG. Notably, this method was entirely different from the traditional means used for preparing other zinc phosphonate. Moreover, it could be deduced that ZnPS-PVPP possessed the potential applications for catalyst supports. In the initial catalytic tests, the catalysts immobilized onto ZnPS-PVPP showed comparable or higher activity and enantioselectivity with that of catalysts reported by our group in the asymmetric epoxidation of unfunctional olefins. - Graphical Abstract: Zinc poly(styrene-phenylvinylphosphonate)-phosphate was a novel type of layered crystalline organic polymer-inorganic hybrid material prepared under mild conditions without addition of any template and could be used as heterogeneous catalyst supports. Highlights: > New types of layered crystalline inorganic-organic polymer hybrid materials zinc poly(styrene-phenylvinylphosphonate-phosphate(ZnPS-PVPP)). > ZnPS-PVPP prepared under mild condition without adding of any template. > Immobilized chiral salen Mn (III) catalysts on ZnPS-PVPP supports show comparative activity and enantioselectivity with that of on ZSPP or ZPS-PVPA.

Authors:
 [1];  [1]; ;  [1]
  1. College of Chemistry and Chemical Engineering Southwest University, Research Institute of Applied Chemistry Southwest University, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of Eco-environments in Three Gorges Reservoir Region Ministry of Education, Chongqing 400715 (China)
Publication Date:
OSTI Identifier:
21580273
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 184; Journal Issue: 9; Other Information: DOI: 10.1016/j.jssc.2011.06.026; PII: S0022-4596(11)00354-9; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADSORPTION; ALKENES; CATALYST SUPPORTS; CATALYSTS; COPOLYMERIZATION; FOURIER TRANSFORMATION; HETEROGENEOUS CATALYSIS; HYBRIDIZATION; INFRARED SPECTRA; NANOSTRUCTURES; ORGANIC POLYMERS; PHOSPHATES; SCANNING ELECTRON MICROSCOPY; STYRENE; TRANSMISSION ELECTRON MICROSCOPY; ZINC; ALKYLATED AROMATICS; AROMATICS; CATALYSIS; CHEMICAL REACTIONS; ELECTRON MICROSCOPY; ELEMENTS; HYDROCARBONS; INTEGRAL TRANSFORMATIONS; METALS; MICROSCOPY; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; POLYMERIZATION; POLYMERS; SORPTION; SPECTRA; TRANSFORMATIONS

Citation Formats

Huang Jing, Fu Xiangkai, E-mail: fxk@swu.edu.cn, Wang Gang, and Miao Qiang. Novel organic polymer-inorganic hybrid material zinc poly(styrene-phenylvinylphosphonate)-phosphate prepared with a simple method. United States: N. p., 2011. Web. doi:10.1016/j.jssc.2011.06.026.
Huang Jing, Fu Xiangkai, E-mail: fxk@swu.edu.cn, Wang Gang, & Miao Qiang. Novel organic polymer-inorganic hybrid material zinc poly(styrene-phenylvinylphosphonate)-phosphate prepared with a simple method. United States. doi:10.1016/j.jssc.2011.06.026.
Huang Jing, Fu Xiangkai, E-mail: fxk@swu.edu.cn, Wang Gang, and Miao Qiang. Thu . "Novel organic polymer-inorganic hybrid material zinc poly(styrene-phenylvinylphosphonate)-phosphate prepared with a simple method". United States. doi:10.1016/j.jssc.2011.06.026.
@article{osti_21580273,
title = {Novel organic polymer-inorganic hybrid material zinc poly(styrene-phenylvinylphosphonate)-phosphate prepared with a simple method},
author = {Huang Jing and Fu Xiangkai, E-mail: fxk@swu.edu.cn and Wang Gang and Miao Qiang},
abstractNote = {A novel type of organic polymer-inorganic hybrid material layered crystalline zinc poly(styrene-phenylvinylphosphonate)-phosphate (ZnPS-PVPP) was synthesized under mild conditions in the absence of any template. And the ZnPS-PVPP were characterized by FT-IR, diffusion reflection UV-vis, AAS, N{sub 2} volumetric adsorption, SEM, TEM and TG. Notably, this method was entirely different from the traditional means used for preparing other zinc phosphonate. Moreover, it could be deduced that ZnPS-PVPP possessed the potential applications for catalyst supports. In the initial catalytic tests, the catalysts immobilized onto ZnPS-PVPP showed comparable or higher activity and enantioselectivity with that of catalysts reported by our group in the asymmetric epoxidation of unfunctional olefins. - Graphical Abstract: Zinc poly(styrene-phenylvinylphosphonate)-phosphate was a novel type of layered crystalline organic polymer-inorganic hybrid material prepared under mild conditions without addition of any template and could be used as heterogeneous catalyst supports. Highlights: > New types of layered crystalline inorganic-organic polymer hybrid materials zinc poly(styrene-phenylvinylphosphonate-phosphate(ZnPS-PVPP)). > ZnPS-PVPP prepared under mild condition without adding of any template. > Immobilized chiral salen Mn (III) catalysts on ZnPS-PVPP supports show comparative activity and enantioselectivity with that of on ZSPP or ZPS-PVPA.},
doi = {10.1016/j.jssc.2011.06.026},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = 9,
volume = 184,
place = {United States},
year = {2011},
month = {9}
}