Modeling of graphite oxidation in a stagnation-point flow field using detailed homogeneous and semiglobal heterogeneous mechanisms with comparisons to experiments

Journal Article · Fri Mar 01 04:00:00 EST 1996 · Combustion and Flame

DOI:https://doi.org/10.1016/0010-2180(95)00151-4· OSTI ID:215661

Chelliah, H K ^[1]; Makino, A; Kato, I; Araki, N ^[2]; Law, C K ^[3]

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1. Univ. of Virginia, Charlottesville, VA (United States). Dept. of Mechanical, Aerospace and Nuclear Engineering
2. Shizuoka Univ., Hamamatsu (Japan). Dept. of Energy and Mechanical Engineering
3. Princeton Univ., NJ (United States). Dept. of Mechanical and Aerospace Engineering

The burning rate of graphite plays a significant role in determining the overall combustion efficiency of coal because of its relatively slow and complex oxidation process. Numerical simulation results are presented on the mass burning rate and the gas-phase flame structure of a heated cylindrical graphite rod in a stagnation-point flow field, using detailed homogeneous chemical kinetics and semiglobal heterogeneous chemical kinetics. Extensive comparisons with new experimental data and data from the literature are shown for various oxidizer compositions, pressures and strain rates. The relative importance of the carbon-radical reactions in the two semiglobal heterogeneous mechanisms employed is demonstrated, while the deficiencies and limitations of applying semiglobal heterogeneous mechanisms for graphite rod oxidations are identified. Under simplifying assumptions, a method for including the graphite porosity in the present quasi-one dimensional formulation is described. The need to develop elementary reaction mechanisms for the heterogeneous kinetics and the importance of accurate estimation of effective surface area is stressed.

• OSTI ID: 215661
• Journal Information: Combustion and Flame, Journal Name: Combustion and Flame Journal Issue: 4 Vol. 104; ISSN CBFMAO; ISSN 0010-2180
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
COAL
COMBUSTION KINETICS
FLAMES
GRAPHITE
MATHEMATICAL MODELS
MORPHOLOGY
ONE-DIMENSIONAL CALCULATIONS
OXIDATION
RODS