Laser photolysis of UF{sub 6} molecules

Journal Article · Tue Aug 31 00:00:00 EDT 1999 · Quantum Electronics (Woodbury, N.Y.)

DOI:https://doi.org/10.1070/QE1999V029N08ABEH001549· OSTI ID:21496534

Baranov, V Yu; Kolesnikov, Yu A; Kotov, A A ^[1]

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1. State Research Center of Russian Federation 'Troitsk Institute for Innovation and Fusion Research', Troitsk, Moscow Region (Russian Federation)

Studies of the photophysical and photochemical processes accompanying the photolysis of UF{sub 6} molecules in the field of UV and IR laser radiation are analysed. The characteristic features of the electronic and vibrational absorption spectra are discussed. The excited states and transitions as well as the molecular deactivation and dissociation channels are identified. The influence of secondary processes on the quantum yield and the photolysis yield is determined. The photolysis of UF{sub 6} molecules in the presence of chemically active reagents and buffer gases is considered. The isotopically selective laser photolysis of UF{sub 6} molecules as a method for the separation of uranium isotopes, as well as other prospects for the application of the laser photolysis of UF{sub 6} molecules in nuclear power engineering, are discussed. (review)

• OSTI ID: 21496534
• Journal Information: Quantum Electronics (Woodbury, N.Y.), Vol. 29, Issue 8; Other Information: DOI: 10.1070/QE1999v029n08ABEH001549; ISSN 1063-7818
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
ABSORPTION SPECTRA
BUFFERS
DEACTIVATION
DISSOCIATION
EXCITED STATES
LASER RADIATION
MOLECULES
PHOTOCHEMISTRY
PHOTOLYSIS
REAGENTS
URANIUM HEXAFLUORIDE
URANIUM ISOTOPES
YIELDS
ACTINIDE COMPOUNDS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ENERGY LEVELS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
ISOTOPES
PHOTOCHEMICAL REACTIONS
RADIATIONS
SPECTRA
URANIUM COMPOUNDS
URANIUM FLUORIDES