Two new hybrid compounds assembled from Keggin-type polyoxometalates and transition metal coordination complexes
- College of Chemistry, Jilin University, Changchun 130023 (China)
Two new hybrid compounds based on Keggin-type polyoxometalates: {l_brace}[PMo{sub 12}O{sub 40}][Ni(Phen){sub 2}(H{sub 2}O)]{sub 2{r_brace}}.K.2OH{sup -} (1) and [Cd{sub 2}(Phen){sub 4}Cl{sub 2}][HPW{sub 12}O{sub 40}].H{sub 2}O (2) (Phen=1,10-phenanthroline), have been prepared and characterized by IR, UV-vis, XPS, XRD and single crystal X-ray diffraction analyses. Compound 1 exhibits a 1-D chain structure constructed from Pseudo-Keggin polyoxometalate bi-supported transition metal coordination complexes linked by K{sup +} ions. Compound 2 contains Pseudo-Keggin polyoxoanions [HPW{sub 12}O{sub 40}]{sup 2-} and novel metal-chloride-ligand coordination complexes [Cd{sub 2}(Phen){sub 4}Cl{sub 2}]{sup 2+}. -- Graphical abstract: Two new hybrid compounds based on different Keggin-type polyoxometalates have been hydrothermally synthesized and characterized by IR, UV-Vis, XPS, XRD, elemental analysis and single crystal X-ray diffraction analysis. Display Omitted Research highlights: {yields} Two hybrids based on Pseudo-Keggin polyanions and metal coordination complexes. {yields} 1-D structure formed by polyanion bisupported metal coordination units linked by K{sup +}. {yields} A metal-chloride-ligand coordination complex [Cd{sub 2}(Phen){sub 4}Cl{sub 2}]{sup 2+}. {yields} A hybrid based on polyanions and metal-chloride-ligand coordination complexes.
- OSTI ID:
- 21494230
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 3 Vol. 184; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
Similar Records
Hydrothermal synthesis and characterization of the tri-capped and mono-supported pseudo-Keggin-type tungstovanadophosphate: {l_brace}PW{sub 4}{sup VI}W{sub 5}{sup V}V{sub 3}{sup IV}O{sub 40}(V{sup IV}O){sub 3}[Cu(en){sub 2}]{r_brace}{sup 6-}
Polyoxometalate immobilization in Cu{sup I}/Ag-pz porous coordination polymers: The influences of them on the structural properties of frameworks
Related Subjects
AROMATICS
AZAARENES
CHLORIDES
CHLORINE COMPOUNDS
COHERENT SCATTERING
COMPLEXES
CRYSTALS
DIFFRACTION
ELECTRON SPECTROSCOPY
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROTHERMAL SYNTHESIS
LIGANDS
MONOCRYSTALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHENANTHROLINES
PHOTOELECTRON SPECTROSCOPY
SCATTERING
SPECTROSCOPY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
X-RAY PHOTOELECTRON SPECTROSCOPY