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Production of copper and brass nanoparticles upon laser ablation in liquids

Journal Article · · Quantum Electronics (Woodbury, N.Y.)
; ;  [1];  [2]
  1. Scientific Center for Wave Studies, A.M.Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)
  2. Laser Materials and Technology Research Center, A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)
The production of nanoparticles upon ablation of copper and brass by pulsed radiation from Nd:YAG and copper lasers in water, ethanol, and acetone is studied. The nanoparticles were investigated by the methods of X-ray diffractometry, optical spectroscopy, and transmission electron microscopy. The produced copper and brass nanoparticles were shown to exhibit a plasmon resonance lying in the visible spectral range near 580 and 510 nm. The brass nanoparticles produced by ablation in ethanol have a shell approximately 10-nm thick for an average dimension of 20-30 nm. A chemical modification of ethanol was observed, which manifested itself in the appearance of intense UV absorption bands. Upon laser irradiation of brass nanoparticles in a liquid their absorption spectrum gradually transformed into the spectrum of copper nanoparticles. (interaction of laser radiation with matter)
OSTI ID:
21470622
Journal Information:
Quantum Electronics (Woodbury, N.Y.), Journal Name: Quantum Electronics (Woodbury, N.Y.) Journal Issue: 10 Vol. 34; ISSN 1063-7818
Country of Publication:
United States
Language:
English