Copper(II) cyanido-bridged bimetallic nitroprusside-based complexes: Syntheses, X-ray structures, magnetic properties, {sup 57}Fe Moessbauer spectroscopy and thermal studies

Journal Article · Sat May 15 00:00:00 EDT 2010 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2010.03.001· OSTI ID:21372589

Travnicek, Zdenek ^[1]; Herchel, Radovan; Mikulik, Jiri ^[1]; Zboril, Radek ^[2]

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1. Department of Inorganic Chemistry, Faculty of Science, Palacky University, Tr. 17. listopadu 12, CZ-771 46 Olomouc (Czech Republic)
2. Department of Physical Chemistry, Faculty of Science, Palacky University, Tr. 17. listopadu 12, CZ-771 46 Olomouc (Czech Republic)

Three heterobimetallic cyanido-bridged copper(II) nitroprusside-based complexes of the compositions [Cu(tet)Fe(CN){sub 5}NO].H{sub 2}O (1), where tet=N,N'-bis(3-aminopropyl)ethylenediamine, [Cu(hto)Fe(CN){sub 5}NO].2H{sub 2}O (2), where hto=1,3,6,9,11,14-hexaazatricyclo[12.2.1.1{sup 6,9}]octadecane and [Cu(nme){sub 2}Fe(CN){sub 5}NO].H{sub 2}O (3), where nme=N-methylethylenediamine, were synthesized and characterized by elemental analyses, {sup 57}Fe Moessbauer and FTIR spectroscopies, thermal analysis, magnetic measurements and single-crystal X-ray analysis. The products of thermal degradation processes of 2 and 3 were studied by XRD, {sup 57}Fe Moessbauer spectroscopy, SEM and EDS, and they were identified as mixtures of CuFe{sub 2}O{sub 4} and CuO. - Three heterobimetallic cyano-bridged copper(II) nitroprusside-based complexes of the general compositions of [Cu(L)Fe(CN){sub 5}NO].xH{sub 2}O, where L=N,N'-bis(3-aminopropyl)ethylenediamine (complex 1), 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1{sup 6,9}]-octadecane (complex 2) and N-methylethylenediamine (complex 3), were synthesized, and fully structurally and magnetically characterized. SEM, EDS, XRD and {sup 57}Fe Moessbauer experiments were used for characterization of thermal decomposition products of complexes 2 and 3.

• OSTI ID: 21372589
• Journal Information: Journal of Solid State Chemistry, Vol. 183, Issue 5; Other Information: DOI: 10.1016/j.jssc.2010.03.001; PII: S0022-4596(10)00075-7; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COPPER COMPLEXES
COPPER OXIDES
CYANIDES
FERRITES
INFRARED SPECTRA
MAGNETIC PROPERTIES
MOESSBAUER EFFECT
PYROLYSIS
SCANNING ELECTRON MICROSCOPY
SPECTROSCOPY
SPINELS
SYNTHESIS
THERMAL ANALYSIS
THERMAL DEGRADATION
X-RAY DIFFRACTION
CHALCOGENIDES
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
COPPER COMPOUNDS
DECOMPOSITION
DIFFRACTION
ELECTRON MICROSCOPY
FERRIMAGNETIC MATERIALS
IRON COMPOUNDS
MAGNETIC MATERIALS
MATERIALS
MICROSCOPY
MINERALS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
SCATTERING
SPECTRA
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS