Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies

Journal Article · Sun Nov 15 04:00:00 EST 2009 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2009.09.004· OSTI ID:21372410

Xiujuan, Jiang ^[1]; Yan, Sun; Guo, Jian-Hua ^[1]; Li, Jin-Shan ^[2]

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1. College of Chemistry and Life Science, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387 (China)
2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)

Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M{sub 2}(mu-H{sub 2}O)(3,4-pybz){sub 4}]{sub n} (M{sup II}=Mn{sup II} for 1, Zn{sup II} for 2, or Cd{sup II} for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schlaefli symbol of (3.4.5)(3{sup 2}.4{sup 4}.5{sup 5}.6{sup 2}.7{sup 2}), whereas [Pb(3,4-pybz){sub 2}]{sub n} (4) shows a completely different 3-D (4{sup 2}.6){sub 2}(4{sup 4}.6{sup 2}.8{sup 9}) framework, which represents a subnet of the (4,8)-connected fluorite lattice. - Graphical abstract: This work presents a series of 3-D metal-organic frameworks with 3-pyridin-4-yl-benzoate, which display new (3,6)-connected net topologies of (3.4.5)(3{sup 2}.4{sup 4}.5{sup 5}.6{sup 2}.7{sup 2}) for Mn{sup II}/Zn{sup II}/Cd{sup II} and (4{sup 2}.6){sub 2}(4{sup 4}.6{sup 2}.8{sup 9}) for Pb{sup II} species.

• OSTI ID: 21372410
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 11 Vol. 182; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
BENZOIC ACID
CADMIUM COMPLEXES
CARBOXYLIC ACIDS
COMPLEXES
EMISSION
FLUORESCENCE
LUMINESCENCE
MANGANESE COMPLEXES
MATHEMATICS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOTON EMISSION
STABILITY
TOPOLOGY
TRANSITION ELEMENT COMPLEXES
ZINC COMPLEXES