Five novel transition metal coordination polymers with 2D/3D framework structure based on flexible H{sub 2}tzda and ancillary ligand bpe

Journal Article · Thu Oct 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2009.07.018· OSTI ID:21372336

Yuting, Wang ^[1]; Yan, Xu ^[2]; Hongwei, Hou ^[2]

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1. Department of Chemistry, Henan Institute of Education, Henan 450014 (China)
2. Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052 (China)

Five new transition metal coordination polymers based on H{sub 2}tzda and co-ligand bpe, {l_brace}[M(tzda)(bpe)].H{sub 2}O{r_brace}{sub n} [M=Zn(1), Cd(2), Mn(3), Co(4)] and [Ni{sub 2}(tzda){sub 2}(bpe){sub 2}(H{sub 2}O)]{sub n} (5) [H{sub 2}tzda=(1,3,4-thiadiazole-2,5-diyldithio)diacetic acid, bpe=1,2-bis(4-pyridyl)ethane], have been hydrothermally synthesized and structurally characterized. Compounds 1-4 feature a 2D-layered architecture generated from [M(tzda)]{sub n} moiety with double-chain structure cross-linking bpe spacers. However, the conformations bpe adopts in 3 and 4 are different from those in 1 and 2 due to the rotation of C-C single bond in bpe. Polymer 5 exhibits an interesting 3D porous framework with 2-fold interpenetration, in which intriguing 1D double helix chains are observed. The photoluminescence properties of 1 and 2 in the solid-state at room temperature are investigated. In addition, variable-temperature magnetic data show weak antiferromagnetic behavior in 3-5. - Graphical abstract: Five new transition metal coordination polymers based on flexible H{sub 2}tzda and bpe have been hydrothermally synthesized and characterized by X-ray diffraction, luminescent emission spectra and low-temperature magnetic measurements, respectively.

• OSTI ID: 21372336
• Journal Information: Journal of Solid State Chemistry, Vol. 182, Issue 10; Other Information: DOI: 10.1016/j.jssc.2009.07.018; PII: S0022-4596(09)00323-5; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CADMIUM COMPLEXES
COBALT COMPLEXES
CROSS-LINKING
EMISSION SPECTRA
HYDROTHERMAL SYNTHESIS
LIGANDS
MANGANESE COMPLEXES
NICKEL COMPLEXES
PHOTOLUMINESCENCE
POLYMERS
POROUS MATERIALS
TEMPERATURE RANGE 0273-0400 K
X-RAY DIFFRACTION
ZINC COMPLEXES
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
EMISSION
LUMINESCENCE
MATERIALS
PHOTON EMISSION
POLYMERIZATION
SCATTERING
SPECTRA
SYNTHESIS
TEMPERATURE RANGE
TRANSITION ELEMENT COMPLEXES