Synthesis, structure and magnetic behavior of a new three-dimensional Manganese phosphite-oxalate: [C{sub 2}N{sub 2}H{sub 10}][Mn{sub 2}{sup II}(OH{sub 2}){sub 2}(HPO{sub 3}){sub 2}(C{sub 2}O{sub 4})]
- Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012 (India)
A novel manganese phosphite-oxalate, [C{sub 2}N{sub 2}H{sub 10}][Mn{sub 2}{sup II}(OH{sub 2}){sub 2}(HPO{sub 3}){sub 2}(C{sub 2}O{sub 4})] has been hydothermally synthesized and its structure determined by single-crystal X-ray diffraction. The structure consists of neutral manganese phosphite layers, [Mn(HPO{sub 3})]{sub i}nfinity, formed by MnO{sub 6} octahedra and HPO{sub 3} units, cross-linked by the oxalate moieties. The organic cations occupy the middle of the 8-membered one-dimensional channels. Magnetic studies indicate weak antiferromagnetic interactions between the Mn{sup 2+} ions. - Abstract: A new antiferromagnetic three-dimensional inorganic-organic hybrid compound, [C{sub 2}N{sub 2}H{sub 10}][Mn{sub 2}{sup II}(OH{sub 2}){sub 2}(HPO{sub 3}){sub 2}(C{sub 2}O{sub 4})] has been prepared hydrothermally. The compound has neutral manganese layers pillared by oxalate units. The neutral manganese layers are shown here. Display Omitted
- OSTI ID:
- 21370582
- Journal Information:
- Journal of Solid State Chemistry, Vol. 182, Issue 9; Other Information: DOI: 10.1016/j.jssc.2009.06.040; PII: S0022-4596(09)00299-0; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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