Organic carboxylate anions effect on the structures of a series of Mn(II) complexes based on 2-phenylimidazo[4,5-f]1,10-phenanthroline ligand

Journal Article · Tue Sep 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2009.06.031· OSTI ID:21370569

Yongqiang, Chen; Guocheng, Liu; Hongyan, Lin; Jinxia, Zhang ^[1]

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1. Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000 (China)

In our efforts to tune the structures of Mn(II) complexes by selection of organic carboxylic acid ligands, six new complexes [Mn(PIP){sub 2}Cl{sub 2}] (1), [Mn(PIP){sub 2}(4,4'-bpdc)(H{sub 2}O)].2H{sub 2}O (2), [Mn(PIP){sub 2}(1,4-bdc)] (3), [Mn(PIP)(1,3-bdc)] (4), [Mn(PIP){sub 2}(2,6-napdc)].H{sub 2}O (5), and [Mn(PIP)(1,4-napdc)].H{sub 2}O (6) were obtained, where PIP=2-phenylimidazo[4,5-f]1,10-phenanthroline, 4,4'-H{sub 2}bpdc=biphenyl-4,4'-dicarboxylic acid, 1,4-H{sub 2}bdc=benzene-1,4-dicarboxylic acid, 1,3-H{sub 2}bdc=benzene-1,3-dicarboxylic acid, 2,6-H{sub 2}napdc=2,6-naphthalenedicarboxylic acid, 1,4-H{sub 2}napdc=1,4-naphthalenedicarboxylic acid. All complexes have been structurally characterized by IR, elemental analyses, and single crystal X-ray diffraction. Structural analyses show that complexes 1 and 2 possess mononuclear structures, complexes 3, 4, and 5 feature chain structures, and complex 6 exhibits a 2D (4,4) network. The structural difference of 1-6 indicates that organic carboxylate anions play important roles in the formation of such coordination architectures. Furthermore, the thermal properties of complexes 1-6 and the magnetic property of 4 have been investigated. - Graphical Abstract: Through selecting organic carboxylate anions, six Mn(II) complexes have been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction.

• OSTI ID: 21370569
• Journal Information: Journal of Solid State Chemistry, Vol. 182, Issue 9; Other Information: DOI: 10.1016/j.jssc.2009.06.031; PII: S0022-4596(09)00286-2; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ANIONS
BENZENE
BIPHENYL
CRYSTAL STRUCTURE
DICARBOXYLIC ACIDS
HYDROTHERMAL SYNTHESIS
LIGANDS
MAGNETIC PROPERTIES
MANGANESE COMPLEXES
MONOCRYSTALS
PHENANTHROLINES
THERMODYNAMIC PROPERTIES
X-RAY DIFFRACTION
AROMATICS
AZAARENES
CARBOXYLIC ACIDS
CHARGED PARTICLES
COHERENT SCATTERING
COMPLEXES
CRYSTALS
DIFFRACTION
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
IONS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHYSICAL PROPERTIES
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPLEXES