Photochromism and visible light induced H{sub 2} generation in Sr{sub 2}TiO{sub 4}:Cr complexes
- Photocatalytic Materials Center, and International Center for Materials Nanoarchitectonics, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)
- Materials Analysis Station, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)
Sr{sub 2}TiO{sub 4}:Cr complexes are found to possess photochromism. After the photochromism, the catalytic performance of the complexes for H{sub 2} generation increases markedly. In fact, it was found that the performance increased more than 20 times compared to the original Sr{sub 2}TiO{sub 4}: 10 mol % Cr complex. These results suggest that it is worthwhile searching and optimizing visible-light-sensitive photocatalysts by investigating possible photochromism.
- OSTI ID:
- 21347323
- Journal Information:
- Applied Physics Letters, Vol. 96, Issue 11; Other Information: DOI: 10.1063/1.3360811; (c) 2010 American Institute of Physics; ISSN 0003-6951
- Country of Publication:
- United States
- Language:
- English
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07 ISOTOPES AND RADIATION SOURCES
CATALYSIS
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PHOTOCHEMISTRY
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CHROMIUM COMPLEXES
HYDROGEN
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ALKALINE EARTH METAL COMPOUNDS
CHEMISTRY
COMPLEXES
ELEMENTS
NONMETALS
OXYGEN COMPOUNDS
STRONTIUM COMPOUNDS
TITANATES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS