Comment on 'Ground state of octahedral platinum hexafluoride'

Journal Article · Fri May 15 00:00:00 EDT 2009 · Physical Review. A

DOI:https://doi.org/10.1103/PHYSREVA.79.056501· OSTI ID:21313161

Gabuda, S P; Kozlova, S G ^[1]

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1. Institute of Inorganic Chemistry of Siberian Department, RAS, Av. Lavrent'eva 3, Novosibirsk 630090 (Russian Federation)

It is shown that the principal results of a recent work by Alvarez-Thon et al. [Phys. Rev. A 77, 034502 (2008)] are in conflict with earlier work of the present authors [JETP Lett. 73, 35 (2001)] and also with a well known result concerning magnetic properties, NMR, and Jahn-Teller effect in the systems possessing even number of d electrons. This can be attributed to the fact that Alvarez-Thon et al. did not account for the influence of {sup 19}F and {sup 195}Pt nuclear magnetic moments and vibronic interactions on the wave function of PtF{sub 6} molecules.

• OSTI ID: 21313161
• Journal Information: Physical Review. A, Vol. 79, Issue 5; Other Information: DOI: 10.1103/PhysRevA.79.056501; (c) 2009 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1050-2947
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
CHEMICAL SHIFT
DIRAC EQUATION
ELECTRONS
FLUORINE 19
GROUND STATES
HARTREE-FOCK METHOD
JAHN-TELLER EFFECT
MAGNETIC PROPERTIES
MOLECULES
NUCLEAR MAGNETIC MOMENTS
NUCLEAR MAGNETIC RESONANCE
PLATINUM
PLATINUM 195
PLATINUM COMPOUNDS
VIBRATIONAL STATES
WAVE FUNCTIONS