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INFRARED SPECTRA OF AMMONIA-WATER ICES

Journal Article · · Astrophysical Journal, Supplement Series
;  [1]
  1. Institute for Astronomy, University of Hawaii, Honolulu, HI 96822 (United States)
We conducted a systematic study of the near-IR and mid-IR spectra of ammonia-water ices at various NH{sub 3}/H{sub 2}O ratios. The differences between the spectra of amorphous and crystalline ammonia-water ices were also investigated. The 2.0 {mu}m ammonia band central wavelength is a function of the ammonia/water ratio. It shifts from 2.006 {+-} 0.003 {mu}m (4985 {+-} 5 cm{sup -1}) to 1.993 {+-} 0.003 {mu}m (5018 {+-} 5 cm{sup -1}) as the percentage of ammonia decreases from 100% to 1%. The 2.2 {mu}m ammonia band center shifts from 2.229 {+-} 0.003 {mu}m (4486 {+-} 5 cm{sup -1}) to 2.208 {+-} 0.003 {mu}m (4528 {+-} 5 cm{sup -1}) over the same range. Temperature-dependent shifts of those bands are below the uncertainty of the measurement, and therefore are not detectable. These results are important for comparison with astronomical observations as well as for estimating the concentration of ammonia in outer solar system ices.
OSTI ID:
21269289
Journal Information:
Astrophysical Journal, Supplement Series, Journal Name: Astrophysical Journal, Supplement Series Journal Issue: 1 Vol. 181; ISSN 0067-0049; ISSN APJSA2
Country of Publication:
United States
Language:
English

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