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Determination of the texture of arrays of aligned carbon nanotubes from the angular dependence of the X-ray emission and X-ray absorption spectra

Journal Article · · Journal of Experimental and Theoretical Physics
; ; ;  [1]; ;  [2]
  1. Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, Siberian Branch (Russian Federation)
  2. Dresden University of Technology, Institute of Solid State Physics (Germany)

The properties of materials containing carbon nanotubes depend on the degree of alignment and the internal structure of nanotubes. It is shown that the degree of misorientation of carbon nanotubes in samples can be evaluated from the measurements of the angular dependences of the carbon X-ray emission and carbon X-ray absorption spectra. The CK{sub {alpha}} emission and CK X-ray absorption spectra of the array of multiwalled carbon nanotubes synthesized by catalytic thermolysis of a mixture of fullerene and ferrocene are measured. A comparison of the calculated model dependences of the relative intensities of the {pi} and {sigma} bands in the spectra with the experimental results makes it possible to evaluate the degree of misorientation of nanotubes in the sample and their internal texture.

OSTI ID:
21244151
Journal Information:
Journal of Experimental and Theoretical Physics, Journal Name: Journal of Experimental and Theoretical Physics Journal Issue: 3 Vol. 107; ISSN JTPHES; ISSN 1063-7761
Country of Publication:
United States
Language:
English

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