Hydrogen dissociation on Pd{sub 4}S surfaces
- National Energy Technology Laboratory, Pittsburgh, PA (United States)
Exposure of Pd-based hydrogen purification membranes to H{sub 2}S, a common contaminant in coal gasification streams, can cause membrane performance to deteriorate, either by deactivating surface sites required for dissociative H{sub 2} adsorption or by forming a low-permeability sulfide scale. In this work, the composition, structure, and catalytic activity of Pd{sub 4}S, a surface scale commonly observed in Pd-membrane separation of hydrogen from sulfur-containing gas streams, were examined using a combination of experimental characterization and density functional theory (DFT) calculations. A Pd{sub 4}S sample was prepared by exposing a 100 mu m Pd foil to H{sub 2}S at 908 K. Both X-ray photoemission depth profiling and low energy ion scattering spectroscopic (LEISS) analysis reveal slight sulfur-enrichment of the top surface of the sample. This view is consistent with the predictions of DFT atomistic thermodynamic calculations, which identified S-terminated Pd{sub 4}S surfaces as energetically favored over corresponding Pd-terminated surfaces. Activation barriers for H-2 dissociation on the Pd{sub 4}S surfaces were calculated. Although barriers are higher than on Pd(111), transition state theory analysis identified reaction pathways on the S-terminated surfaces for which hydrogen dissociation rates are high enough to sustain the separation process at conditions relevant to gasification applications.
- OSTI ID:
- 21240482
- Journal Information:
- Journal of Physical Chemistry C, Journal Name: Journal of Physical Chemistry C Journal Issue: 43 Vol. 113; ISSN 1932-7447
- Country of Publication:
- United States
- Language:
- English
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