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TiO{sub 2}-containing cement pastes and mortars: Measurements of the photocatalytic efficiency using a rhodamine B-based colourimetric test

Journal Article · · Solar Energy
;  [1]; ;  [2];  [3]
  1. Universite Paris-Est, Centre Scientifique et Technique du Batiment (CSTB), Departement Enveloppe et Revetements, 24, rue Joseph Fourier, 38400 Saint-Martin-d'Heres (France)
  2. CTG Italcementi Group, rue des Technodes, 78931 Guerville Cedex (France)
  3. Axim Technology Center, P.O. Box 234, 8282 Middlebranch Road, Middlebranch, Ohio 44652 (United States)

The photocatalytic activities of cement pastes and mortars, containing various amounts of titanium dioxide (TiO{sub 2}) in the anatase form, were evaluated and compared. The density, total porosity and pore size distribution of the materials were measured, and the amount of TiO{sub 2} being at their surfaces was estimated. The photocatalytic efficiency was evaluated by monitoring the discolouration of rhodamine B applied to the surface of the materials which were then exposed to artificial sun light; this evaluation was based on the use of a dimensionless specific activity coefficient. For TiO{sub 2} contents higher than 1 wt% (up to 5 wt%), cement pastes exhibited a photocatalytic activity higher than that of mortars because their activity was roughly proportional to the TiO{sub 2} content, whereas the activity of mortars levelled off. On the other hand, the type of cement used to prepare the materials had a low effect on the photocatalytic performances. (author)

OSTI ID:
21227413
Journal Information:
Solar Energy, Journal Name: Solar Energy Journal Issue: 10 Vol. 83; ISSN 0038-092X; ISSN SRENA4
Country of Publication:
United States
Language:
English

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