Impact of catalyst metal-acid balance in n-hexadecane hydroisomerization and hydrocracking
- Mobil Research and Development Corp., Princeton, NJ (United States). Central Research Lab.
The reaction pathways and kinetics of n-hexadecane hydroisomerization and hydrocracking were determined in the presence of each of three platinum-containing dual-function catalysts: (a) Pt on a proprietary zeolite (Pt/Z), (b) Pt on silica-alumina (Pt/Si-Al), and (c) Pt on MCM-41 (Pt/MCM-41). The reaction networks were used to interpret differences in isomerization selectivity. The low isomerization selectivity observed in the presence of Pt/Si-Al was shown to be a consequence of changes in both relative isomerization/cracking rates and reaction pathways. Using the classical bifunctional reaction scheme, the changes in pathway were hypothesized to be consistent with changes in the relative concentrations of metal and acid sites (i.e., the metal-acid balance). On the basis of a recently proposed model of dual-function catalysis, the different observed pathways were subsequently shown to be those expected in two limiting cases of the metal-acid balance. The simplified quantitative picture given here provides a preliminary basis for relating catalyst preparation variables to catalyst performance for dual-function catalysts.
- OSTI ID:
- 212205
- Journal Information:
- Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 2 Vol. 35; ISSN IECRED; ISSN 0888-5885
- Country of Publication:
- United States
- Language:
- English
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