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Mixed potential type NO{sub x} sensor based on stabilized zirconia and oxide electrode

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1836448· OSTI ID:212141
; ;  [1]; ;  [2]
  1. Kyushu Univ., Kasuga, Fukuoka (Japan)
  2. Riken Corp., Kumagaya, Saitama (Japan)
A new solid-state NO{sub x} sensor operative at high temperature was designed using stabilized zirconia and an oxide sensing electrode. Among the various oxides examined, CdMn{sub 2}O{sub 4} was found to be the most excellent material for NO{sub x} sensing at 500 C. The EMF values of the sensor were almost linear to the logarithm of NO{sub x} concentration with a positive slope for NO{sub 2} and a negative slope for NO. A nitrogen oxide sensing mechanism involving mixed potential was proposed based on the measurements of polarization curves.
Sponsoring Organization:
USDOE
OSTI ID:
212141
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 2 Vol. 143; ISSN JESOAN; ISSN 0013-4651
Country of Publication:
United States
Language:
English

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