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Title: Preparation, structural and magnetic characterization of DyCrMnO{sub 5}

Abstract

The title compound has been first synthesized by a citrate technique followed by thermal treatments under moderate oxygen pressure conditions, and characterized by X-ray and neutron powder diffraction (NPD) and magnetization measurements. The crystal structure of DyCrMnO{sub 5} has been refined from NPD data in the space group Pbam; a=7.2617(6) A, b=8.5161(6) A, and c=5.7126(5) A at 295 K. This oxide is isostructural with RMn{sub 2}O{sub 5} oxides (R=rare earths) and it contains infinite chains of (Cr, Mn){sup 4+}O{sub 6} octahedra-sharing edges, linked together by (Mn, Cr){sup 3+}O{sub 5} pyramids and DyO{sub 8} units. The high degree of antisite disordering exhibited by DyCrMnO{sub 5} is noteworthy. The octahedral positions are occupied by roughly 50% of Mn and Cr cations, and the pyramidal groups contain two thirds of Mn and one third of Cr cations. We assume that Mn and Cr cations at the octahedral positions exhibit a tetravalent oxidation state, whereas the metals at the pyramidal positions are trivalent, in order to preserve the electroneutrality of this oxide. The susceptibility vs temperature curve of DyCrMnO{sub 5} does not suggest the establishment of a long-range magnetic structure even at low temperatures; the NPD technique does not provide any signal of magneticmore » ordering, since the reflections do not show any magnetic contribution. - Graphical abstract: DyCrMnO{sub 5} is isostructural with DyMn{sub 2}O{sub 5}, belonging to the Pbam space group. The crystal structure contains infinite chains of edge-sharing Mn{sup 4+}O{sub 6} octahedra, interconnected by dimer units of Cr{sup 3+}O{sub 5} square pyramids. The low-temperature neutron powder diffraction (NPD) patterns do not show any magnetic contribution, indicating that a full long-range magnetic ordering is not established down to low temperature, although the Dy{sup 3+} magnetic moments are susceptible to be polarized by an external magnetic field at the lowest temperature of 5 K.« less

Authors:
 [1];  [2]; ;  [1]
  1. Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid (Spain)
  2. Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid (Spain), E-mail: mretuerto@icmm.csic.es
Publication Date:
OSTI Identifier:
21212225
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 182; Journal Issue: 3; Other Information: DOI: 10.1016/j.jssc.2008.11.023; PII: S0022-4596(08)00605-1; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHROMIUM COMPOUNDS; CHROMIUM IONS; CRYSTAL STRUCTURE; DYSPROSIUM COMPOUNDS; DYSPROSIUM IONS; HEAT TREATMENTS; MAGNETIC FIELDS; MAGNETIC MOMENTS; MAGNETIZATION; MANGANESE COMPOUNDS; MANGANESE IONS; NEUTRON DIFFRACTION; OXIDES; SPACE GROUPS; TEMPERATURE RANGE 0000-0013 K; TEMPERATURE RANGE 0273-0400 K

Citation Formats

Martinez-Lope, M.J., Retuerto, M., Garcia-Hernandez, M., and Alonso, J.A. Preparation, structural and magnetic characterization of DyCrMnO{sub 5}. United States: N. p., 2009. Web. doi:10.1016/j.jssc.2008.11.023.
Martinez-Lope, M.J., Retuerto, M., Garcia-Hernandez, M., & Alonso, J.A. Preparation, structural and magnetic characterization of DyCrMnO{sub 5}. United States. doi:10.1016/j.jssc.2008.11.023.
Martinez-Lope, M.J., Retuerto, M., Garcia-Hernandez, M., and Alonso, J.A. Sun . "Preparation, structural and magnetic characterization of DyCrMnO{sub 5}". United States. doi:10.1016/j.jssc.2008.11.023.
@article{osti_21212225,
title = {Preparation, structural and magnetic characterization of DyCrMnO{sub 5}},
author = {Martinez-Lope, M.J. and Retuerto, M. and Garcia-Hernandez, M. and Alonso, J.A.},
abstractNote = {The title compound has been first synthesized by a citrate technique followed by thermal treatments under moderate oxygen pressure conditions, and characterized by X-ray and neutron powder diffraction (NPD) and magnetization measurements. The crystal structure of DyCrMnO{sub 5} has been refined from NPD data in the space group Pbam; a=7.2617(6) A, b=8.5161(6) A, and c=5.7126(5) A at 295 K. This oxide is isostructural with RMn{sub 2}O{sub 5} oxides (R=rare earths) and it contains infinite chains of (Cr, Mn){sup 4+}O{sub 6} octahedra-sharing edges, linked together by (Mn, Cr){sup 3+}O{sub 5} pyramids and DyO{sub 8} units. The high degree of antisite disordering exhibited by DyCrMnO{sub 5} is noteworthy. The octahedral positions are occupied by roughly 50% of Mn and Cr cations, and the pyramidal groups contain two thirds of Mn and one third of Cr cations. We assume that Mn and Cr cations at the octahedral positions exhibit a tetravalent oxidation state, whereas the metals at the pyramidal positions are trivalent, in order to preserve the electroneutrality of this oxide. The susceptibility vs temperature curve of DyCrMnO{sub 5} does not suggest the establishment of a long-range magnetic structure even at low temperatures; the NPD technique does not provide any signal of magnetic ordering, since the reflections do not show any magnetic contribution. - Graphical abstract: DyCrMnO{sub 5} is isostructural with DyMn{sub 2}O{sub 5}, belonging to the Pbam space group. The crystal structure contains infinite chains of edge-sharing Mn{sup 4+}O{sub 6} octahedra, interconnected by dimer units of Cr{sup 3+}O{sub 5} square pyramids. The low-temperature neutron powder diffraction (NPD) patterns do not show any magnetic contribution, indicating that a full long-range magnetic ordering is not established down to low temperature, although the Dy{sup 3+} magnetic moments are susceptible to be polarized by an external magnetic field at the lowest temperature of 5 K.},
doi = {10.1016/j.jssc.2008.11.023},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = 3,
volume = 182,
place = {United States},
year = {2009},
month = {3}
}