Syntheses and characterization of novel lanthanide adamantine-dicarboxylate coordination complexes
- Institute of Solid Materials Chemistry, State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211 (China)
Hydrothermal reactions of 1,10-phenanthroline (phen), 1,3-adamantanedicarboxylic acid (H{sub 2}L) and lanthanide chlorides yielded six compounds: [Ln(L)(HL)(phen)] (Ln=Pr, 1; Nd, 2), [Ln(L)(HL)(phen)(H{sub 2}O)] (Sm, 3; Eu, 4), [Tb(L)(HL)(phen)(H{sub 2}O)]{sub 2}.2H{sub 2}O (5), [Er{sub 3}(L){sub 4}(OH)(phen)]{sub 2} (6). Compounds 1-4 are structurally featured by one-dimensional polymeric chains; 5 hold binuclear structure constructed from eight-coordinated lanthanide center LnN{sub 2}O{sub 6} of distorted bicapped trigonal prism bridged by dicarboxylate ligands; 6 shows that erbium ions are in mono and bicapped trigonal prismatic geometries, respectively, which are further connected by {mu}{sub 3}-OH to give rise to trinuclear structure. Thermogravimetric analyses of 1, 3 and 5 were performed. Fluorescent measurements of 4 and 5 were carried out, respectively. - Grapical Abstract: Hydrothermal reactions of 1,10-phenanthroline, 1,3-adamantanedicarboxylic acid and lanthanide choloride yielded a novel supramolecular architectures constructed from polyhedral LnN{sub 2}O{sub 6} of distorted bicapped trigonal prism bridged by dicarboxylate.
- OSTI ID:
- 21212162
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 1 Vol. 182; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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