Coherent stimulated x-ray Raman spectroscopy: Attosecond extension of resonant inelastic x-ray Raman scattering

Journal Article · Sun Feb 15 04:00:00 EST 2009 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PHYSREVB.79.085108· OSTI ID:21192541

Harbola, Upendra ^[1]; Mukamel, Shaul ^[2]

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1. Department of Chemistry and Biochemistry, University of California-San Diego, San Diego, California 92093-0340 (United States)
2. Department of Chemistry, University of California-Irvine, Irvine, California 92697-2025 (United States)

Spontaneous and stimulated resonant inelastic x-ray Raman-scattering signals are calculated using the Keldysh-Schwinger closed-time path loop and expressed as overlaps of doorway and window electron-hole wave packets. These are recast in terms of the one-particle Green's functions and expansion coefficients of configuration-interaction singles for valence excitations, which can be obtained from standard electronic structure codes. Calculation for many-body states of ground and core-excited systems is avoided.

• OSTI ID: 21192541
• Journal Information: Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 8 Vol. 79; ISSN 1098-0121
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
CONFIGURATION INTERACTION
ELECTRONIC STRUCTURE
EXCITATION
EXPANSION
GREEN FUNCTION
GROUND STATES
MANY-BODY PROBLEM
PARTICLES
RAMAN EFFECT
RAMAN SPECTRA
RAMAN SPECTROSCOPY
SCATTERING
VALENCE
WAVE PACKETS
X RADIATION
X-RAY SPECTRA