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Title: Negative-U property of interstitial hydrogen in GaAs

Journal Article · · Physical Review. B, Condensed Matter and Materials Physics
; ; ;  [1]
  1. Department of Physics and Astronomy, University of Aarhus, DK-8000 Aarhus C (Denmark)

We identify the donor level of interstitial hydrogen in GaAs, which is characterized by the activation enthalpy E{sub C}-E{sub t}=0.13 eV. This level is the marker of two different but closely related defect structures, which are indistinguishable as far as their emission properties are concerned; however, discernible on the basis of their different dynamical behaviors are revealed by annealing studies. We interpret the two structures as regular bond center hydrogen H(BC) and bond center hydrogen H(BC{sup '}), which is perturbed by the local strain from a neighbor point defect. We demonstrate negative-U properties of the perturbed structure and infer that the corresponding acceptor H(T{sup '}) lies deep in the band gap. These results for interstitial hydrogen in GaAs are in every aspect analogous to the properties of interstitial hydrogen in Si.

OSTI ID:
21143596
Journal Information:
Physical Review. B, Condensed Matter and Materials Physics, Vol. 78, Issue 3; Other Information: DOI: 10.1103/PhysRevB.78.035211; (c) 2008 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1098-0121
Country of Publication:
United States
Language:
English