Synthesis and characterization of a new layered organic-inorganic hybrid nickel(II) 1,4:5,8-naphthalenediimide bis-phosphonate, exhibiting canted antiferromagnetism, with T{sub c}{approx}21 K

Journal Article · Thu May 15 04:00:00 EDT 2008 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2008.02.014· OSTI ID:21128300

Bellitto, Carlo ^[1]; Righini, Guido ^[1]

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1. Istituto di Struttura della Materia del CNR, Sez. di Montelibretti, Via Salaria km 29.3, I-00016 Monterotondo Stazione (Italy)

A new Ni(II) layered hybrid organic-inorganic compound of formula Ni{sub 2}[(NDI-BP)(H{sub 2}O){sub 2}].2H{sub 2}O has been prepared in very mild conditions from N,N'-bis(2-phosphonoethyl)napthalene-1,4:5,8-tetracarboximide (NDI-BP ligand) and NiCl{sub 2}. The X-ray powder structure characterization of the title compound suggests a pillared layered organic-inorganic hybrid structure. The distance between the organic and inorganic layers has been found to be 17.8 A. The inorganic layers consist of corner sharing [NiO{sub 5}(H{sub 2}O)] octahedra and they are pillared by the diphosphonate groups. DC and AC magnetic measurements as a function of temperature and field indicate the presence of 2D antiferromagnetic exchange interactions between the nearest-neighbor Ni(II) ions below 100 K. A long-range magnetic ordering at T{sub c}{approx}21 K has been established and is attributed to the presence of spin canting. AC magnetic measurements as a function of temperature at different frequencies confirm the occurrence of the magnetic ordering temperature at T=21 K and the presence of a slight structural disorder in the title compound. - Graphical abstract: A new layered hybrid organic-inorganic Ni(II) N,N'-bis(2-phosphonoethyl)-naphthalene 1,4:5,8 tetracarboxydiimide complex has been synthesized and characterized. Magnetic measurements as a function of temperature and at different fields show that the compound is magnetically ordered below T{sub c}{approx}21 K.

• OSTI ID: 21128300
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 5 Vol. 181; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ANTIFERROMAGNETISM
CONDENSED AROMATICS
EXCHANGE INTERACTIONS
LAYERS
LIGANDS
MAGNETIZATION
NICKEL CHLORIDES
NICKEL COMPLEXES
PHOSPHONATES
SPIN
SYNTHESIS
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE 0013-0065 K
TEMPERATURE RANGE 0065-0273 K
X RADIATION