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Title: Performance of copper chloride-impregnated sorbents on mercury vapor control in an entrained-flow reactor system

Journal Article · · Journal of the Air and Waste Management Association
OSTI ID:21125951
; ;  [1]
  1. University of Cincinnati, Cincinnati, OH (United States). Department of Civil and Environmental Engineering

An entrained-flow system has been designed and constructed to simulate in-flight mercury (Hg) capture by sorbent injection in ducts of coal-fired utility plants. The test conditions of 1.2-sec residence time, 140{degree}C gas temperature, 6.7 m/sec (22 ft/sec) gas velocity, and 0-0.24 g/m{sup 3} (0-15 lbs of sorbent per 1 million actual cubic feet of flue gas sorbent injection rates were chosen to simulate conditions in the ducts. Four kinds of sorbents were used in this study. Darco Hg-LH (lignite-based) served as a benchmark sorbent with which Hg control capability of other sorbents could be compared. Also, Darco-FGD (lignite-based) was used as a representative raw activated carbon sorbent. Two different copper chloride-impregnated sorbents were developed in the laboratory and tested in the entrained-flow system to examine the possibility of using these sorbents at coal-fired power plants. The test results showed that one of the copper chloride sorbents has remarkable elemental mercury (Hg{sup 0}) oxidation capability, and the other sorbent demonstrated a better performance in Hg removal than Darco Hg-LH. 13 refs., 4 figs., 3 tabs.

OSTI ID:
21125951
Journal Information:
Journal of the Air and Waste Management Association, Vol. 58, Issue 11; Other Information: Tim.Keener@uc.edu; ISSN 1047-3289
Country of Publication:
United States
Language:
English