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Propagation of complex shaped ultrafast pulses in highly optically dense samples

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.2894871· OSTI ID:21104029
;  [1];  [2];  [3]
  1. Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States)
  2. Department of Chemistry, Duke University, Durham, North Carolina 27708 (United States)
  3. Department of Chemistry, Indian Institute of Technology, Kanpur 208016 (India)
We examine the propagation of shaped (amplitude- and frequency-modulated) ultrafast laser pulses through optically dense rubidium vapor. Pulse reshaping, stimulated emission dynamics, and residual electronic excitation all strongly depend on the laser pulse shape. For example, frequency swept pulses, which produce adiabatic passage in the optically thin limit (independent of the sign of the frequency sweep), behave unexpectedly in optically dense samples. Paraxial Maxwell optical Bloch equations can model our ultrafast pulse propagation results well and provide insight.
OSTI ID:
21104029
Journal Information:
Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 15 Vol. 128; ISSN JCPSA6; ISSN 0021-9606
Country of Publication:
United States
Language:
English

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