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Title: Crystal structure of tetraphenylphosphonium 2-{l_brace}[(Z)-Hydroxy(phenyl)methylene]ammonio{r_brace}nonahydro-closo-Decaborate: The intramolecular O-H...B{sub 3} hydrogen bond in the [B{sub 10}H{sub 9}NHC(OH)Ph]{sup -} anion

Abstract

The compound (PPh{sub 4})[B{sub 10}H{sub 9}NHC(OH)Ph] is synthesized and its X-ray diffraction study is performed (120 K, R = 0.0875 for 5531 observed reflections). The NHC(OH)Ph substituent occupies the equatorial position in the polyhedral anion. The orientation of the substituent is stabilized by the intramolecular specific interaction of the OH group with the B atoms of the apical B(1)B(2)B(3) face, which can be considered as a multicenter hydrogen bond (the O...B distances are 3.001, 2.877, and 3.251 A; the H...B distances are 2.00, 2.18, and 2.30 A; and the O-H...B angles are 156{sup o}, 121{sup o}, and 148{sup o})

Authors:
; ;  [1]
  1. Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation)
Publication Date:
OSTI Identifier:
21090943
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 52; Journal Issue: 2; Other Information: DOI: 10.1134/S1063774507020186; Copyright (c) 2007 Nauka/Interperiodica; Article Copyright (c) 2007 Pleiades Publishing, Inc; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANIONS; BORATES; CRYSTAL STRUCTURE; INTERACTIONS; TEMPERATURE RANGE 0065-0273 K; X-RAY DIFFRACTION

Citation Formats

Polyakova, I. N., E-mail: polyakova@igic.ras.ru, Zhizhin, K. Yu., and Kuznetsov, N. T.. Crystal structure of tetraphenylphosphonium 2-{l_brace}[(Z)-Hydroxy(phenyl)methylene]ammonio{r_brace}nonahydro-closo-Decaborate: The intramolecular O-H...B{sub 3} hydrogen bond in the [B{sub 10}H{sub 9}NHC(OH)Ph]{sup -} anion. United States: N. p., 2007. Web. doi:10.1134/S1063774507020186.
Polyakova, I. N., E-mail: polyakova@igic.ras.ru, Zhizhin, K. Yu., & Kuznetsov, N. T.. Crystal structure of tetraphenylphosphonium 2-{l_brace}[(Z)-Hydroxy(phenyl)methylene]ammonio{r_brace}nonahydro-closo-Decaborate: The intramolecular O-H...B{sub 3} hydrogen bond in the [B{sub 10}H{sub 9}NHC(OH)Ph]{sup -} anion. United States. doi:10.1134/S1063774507020186.
Polyakova, I. N., E-mail: polyakova@igic.ras.ru, Zhizhin, K. Yu., and Kuznetsov, N. T.. Thu . "Crystal structure of tetraphenylphosphonium 2-{l_brace}[(Z)-Hydroxy(phenyl)methylene]ammonio{r_brace}nonahydro-closo-Decaborate: The intramolecular O-H...B{sub 3} hydrogen bond in the [B{sub 10}H{sub 9}NHC(OH)Ph]{sup -} anion". United States. doi:10.1134/S1063774507020186.
@article{osti_21090943,
title = {Crystal structure of tetraphenylphosphonium 2-{l_brace}[(Z)-Hydroxy(phenyl)methylene]ammonio{r_brace}nonahydro-closo-Decaborate: The intramolecular O-H...B{sub 3} hydrogen bond in the [B{sub 10}H{sub 9}NHC(OH)Ph]{sup -} anion},
author = {Polyakova, I. N., E-mail: polyakova@igic.ras.ru and Zhizhin, K. Yu. and Kuznetsov, N. T.},
abstractNote = {The compound (PPh{sub 4})[B{sub 10}H{sub 9}NHC(OH)Ph] is synthesized and its X-ray diffraction study is performed (120 K, R = 0.0875 for 5531 observed reflections). The NHC(OH)Ph substituent occupies the equatorial position in the polyhedral anion. The orientation of the substituent is stabilized by the intramolecular specific interaction of the OH group with the B atoms of the apical B(1)B(2)B(3) face, which can be considered as a multicenter hydrogen bond (the O...B distances are 3.001, 2.877, and 3.251 A; the H...B distances are 2.00, 2.18, and 2.30 A; and the O-H...B angles are 156{sup o}, 121{sup o}, and 148{sup o})},
doi = {10.1134/S1063774507020186},
journal = {Crystallography Reports},
number = 2,
volume = 52,
place = {United States},
year = {Thu Mar 15 00:00:00 EDT 2007},
month = {Thu Mar 15 00:00:00 EDT 2007}
}