EXAFS spectroscopy of quasicrystals

Journal Article · Thu Nov 15 04:00:00 EST 2007 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774507060120· OSTI ID:21090721

Rakshun, Ya V ^[1]

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1. Russian Academy of Sciences, Budker Institute of Nuclear Physics, Siberian Branch (Russian Federation)

The results of the investigation of the features of the local structure of quasicrystalline materials by extended X-ray absorption fine structure (EXAFS) spectroscopy with the use of synchrotron radiation are analyzed. The advantages of this method from the point of view of deriving information about the local shifts of the atoms forming an icosahedral structure are demonstrated. The rearrangement of the local environment of copper and iron in Al-Fe-Cu ternary alloys at a transition from the crystalline to the quasicrystalline phase has been investigated. It is established that the nearest copper coordination retains the symmetry characteristic of the crystal; however, rotation and small displacements of copper matrix atoms lead to significant rearrangement of aluminum atoms around iron atoms. As a result, icosahedral clusters with pentagonal symmetry are formed around iron atoms and violation of the translational symmetry is accompanied by the transition of Al-Fe-Cu to the quasicrystalline state.

• OSTI ID: 21090721
• Journal Information: Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 6 Vol. 52; ISSN CYSTE3; ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ABSORPTION SPECTROSCOPY
ALUMINIUM ALLOYS
COPPER ALLOYS
FINE STRUCTURE
IRON ALLOYS
SYNCHROTRON RADIATION
TERNARY ALLOY SYSTEMS
X-RAY SPECTROSCOPY