Conditions for superconductivity in the electron-doped copper-oxide system, (Nd{sub 1-x}Ce{sub x}){sub 2}CuO{sub 4+{delta}}
Journal Article
·
· Journal of Solid State Chemistry
- Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 (Japan)
We report systematic studies on the relations among the Ce{sup IV}-for-Nd{sup III} substitution level (x), oxygen-partial pressure (P{sub O{sub 2}}), oxygen content (4+{delta}), lattice parameters (a, c) and superconductivity characteristics (T{sub c}, volume fraction) in the (Nd{sub 1-x}Ce{sub x}){sub 2}Cu{sub 1-y}O{sub 4+{delta}} system which includes electron-doped superconductors. Independent of the Ce-doping level x, samples synthesized in air are found oxygen deficient, i.e. {delta}<0. Nevertheless, reductive annealing is needed to induce superconductivity in the air-synthesized samples. At the same time, the amount of oxygen removed upon the annealing is found very small (e.g. 0.004 oxygen atoms per formula unit at x=0.075), and consequently the effect of the annealing on the valence of copper (and thereby also on the electron doping level) is insignificant. Rather, the main function of the reductive annealing is likely to repair the Cu vacancies believed to exist in tiny concentrations (y) in the air-synthesized samples. - Graphical abstract: Superconductivity in the electron-doped (Nd{sub 1-x}Ce{sub x}){sub 2}Cu{sub 1-y}O{sub 4+{delta}} system is sensitively controlled not only by the Ce{sup IV}-for-Nd{sup III} substitution level (x) but also by the the Cu-vacancy concentration (y) and the oxygen content ({delta}) determined by oxygen-partial pressure used for the post-annealing.
- OSTI ID:
- 21043900
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 2 Vol. 181; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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