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Interference effects in above-threshold ionization from diatomic molecules: Determining the internuclear separation

Journal Article · · Physical Review. A
 [1];  [2]
  1. Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, 69117 Heidelberg (Germany)
  2. Max-Born-Institut fuer Nichtlineare Optik und Kurzzeitspektroskopie, Max-Born-Strasse 2A, D-12489 Berlin (Germany)

We calculate angle-resolved above-threshold ionization spectra for diatomic molecules in linearly polarized laser fields, employing the strong-field approximation. The interference structure resulting from the individual contributions of the different scattering scenarios is discussed in detail, with respect to the dependence on the internuclear distance and molecular orientation. We show that, in general, the contributions from the processes in which the electron is freed at one center and rescatters off the other obscure the interference maxima and minima obtained from single-center processes. However, around the boundary of the energy regions for which rescattering has a classical counterpart, such processes play a negligible role and very clear interference patterns are observed. In such energy regions, one is able to infer the internuclear distance from the energy difference between adjacent interference minima.

OSTI ID:
21015998
Journal Information:
Physical Review. A, Journal Name: Physical Review. A Journal Issue: 2 Vol. 76; ISSN 1050-2947; ISSN PLRAAN
Country of Publication:
United States
Language:
English

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