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Direct synthesis of sp-bonded carbon chains on graphite surface by femtosecond laser irradiation

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.2793628· OSTI ID:21013656
; ; ;  [1]
  1. Department of Physics, University of Waterloo, 200 University Ave. West Waterloo, Ontario N2L 3G1 (Canada)

Microscopic phase transformation from graphite to sp-bonded carbon chains (carbyne) and nanodiamond has been induced by femtosecond laser pulses on graphite surface. UV/surface enhanced Raman scattering spectra and x-ray photoelectron spectra displayed the local synthesis of carbyne in the melt zone while nanocrystalline diamond and trans-polyacetylene chains form in the edge area of gentle ablation. These results evidence possible direct 'writing' of variable chemical bonded carbons by femtosecond laser pulses for carbon-based applications.

OSTI ID:
21013656
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 13 Vol. 91; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English