Carbonyl derivatives of chloride-dimethyl sulfoxide-ruthenium (II) complexes: Synthesis, structural characterization, and reactivity of Ru(CO){sub x}(DMSO){sub 4-x}Cl{sub 2} complexes (x = 1-3)
- Universita de Trieste (Italy); and others
The reactivity of cis- and trans-RuCl{sub 2}(DMSO){sub 4} with carbon monoxide has been thoroughly investigated. Depending on the choice of the solvent and the reaction conditions, cis-RuCl{sub 2}(DMSO){sub 4} reacts with CO at ambient pressure replacing one, two or three DMSO molecules.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 210096
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 19 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
Similar Records
Carbonyl derivatives of chloride-dimethyl sulfoxide-ruthenium(III) complexes: Synthesis, crystal structure, and reactivity of [(DMSO){sub 2}H][trans-RuCl{sub 4}(DMSO)(CO)] and mer,cis-RuCl{sub 3}(DMSO){sub 2}(CO)
cis- and trans-Dihalotetrakis(dimethyl sulfoxide)ruthenium(II) complexes (RuX/sub 2/(DMSO)/sub 4/; X = Cl, Br): Synthesis, structure, and antitumor activity
Kinetic and thermodynamic stabilities of the geometric isomers of (R/sub 3/P)/sub 2/Ru(CO)/sub 2/Cl/sub 2/ and (R/sub 3/P)/sub 3/Ru(CO)Cl/sub 2/ complexes
Journal Article
·
Wed Sep 13 00:00:00 EDT 1995
· Inorganic Chemistry
·
OSTI ID:210095
cis- and trans-Dihalotetrakis(dimethyl sulfoxide)ruthenium(II) complexes (RuX/sub 2/(DMSO)/sub 4/; X = Cl, Br): Synthesis, structure, and antitumor activity
Journal Article
·
Tue Nov 15 23:00:00 EST 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5722066
Kinetic and thermodynamic stabilities of the geometric isomers of (R/sub 3/P)/sub 2/Ru(CO)/sub 2/Cl/sub 2/ and (R/sub 3/P)/sub 3/Ru(CO)Cl/sub 2/ complexes
Journal Article
·
Tue Nov 15 23:00:00 EST 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5974248