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Analysis of trends in episodic acidification of streams in western Maryland

Journal Article · · Environmental Science and Technology
DOI:https://doi.org/10.1021/es070424u· OSTI ID:20947223
; ; ;  [1]
  1. University of Maryland Center for Environmental Science, Frostburg, MD (United States). Appalachian Laboratory

In this study we report on changes in the magnitude and mechanisms of episodic acidification of a small acid-sensitive stream in western Maryland (U.S.) during the 1990s, a period in which wet sulfate deposition declined by 10-25% due to implementation of the Clean Air Act Amendments (CAAA) of 1990. We observed a relatively minor trend in the magnitude of episodic acidification over this period, as measured by transient changes in acid neutralizing capacity ({Delta}ANC) and minimum values of ANC (ANC{sub min}) during 22 events sampled prior to and following CAAA implementation. Any relationship to changes in atmospheric deposition appears to be confounded by large hydroclimatological variability between the two sampling periods. Nonetheless, results obtained prior to implementation of the CAAA indicated that the mechanism of episodic acidification was mostly attributable to flushing of accumulated sulfate from the watershed, whereas results obtained post-CAAA indicated domination by base cation dilution. This shift in the mechanism of episodic acidification is qualitatively consistent with hydrochemical theory, as well as with empirical results from surface waters in other regions where dramatic declines in sulfate deposition have taken place. 31 refs., 5 figs., 1 tab.

OSTI ID:
20947223
Journal Information:
Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 16 Vol. 41; ISSN ESTHAG; ISSN 0013-936X
Country of Publication:
United States
Language:
English