In situ X-ray powder diffraction, synthesis, and magnetic properties of InVO{sub 3}

Journal Article · Thu Dec 14 23:00:00 EST 2006 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2006.07.037· OSTI ID:20900900

Lundgren, Rylan J ^[1]; Cranswick, Lachlan M.D. ^[2]; Bieringer, Mario ^[1]

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1. Department of Chemistry, University of Manitoba, Winnipeg, MB, R3T 2N2 (Canada)
2. Canadian Neutron Beam Centre, National Research Council Canada, Chalk River Laboratories, Chalk River, Ont., K0J 1J0 (Canada)

We report the first synthesis and high-temperature in situ X-ray diffraction study of InVO{sub 3}. Polycrystalline InVO{sub 3} has been prepared via reduction of InVO{sub 4} using a carbon monoxide/carbon dioxide buffer gas. InVO{sub 3} crystallizes in the bixbyite structure in space group Ia-3 (206) with a=9.80636(31) A with In{sup 3+}/V{sup 3+} disorder on the (8b) and (24d) cation sites. In situ powder X-ray diffraction experiments and thermal gravimetric analysis in a CO/CO{sub 2} buffer gas revealed the existence of the metastable phase InVO{sub 3}. Bulk samples with 98.5(2)% purity were prepared using low-temperature reduction methods. The preparative methods limited the crystallinity of this new phase to approximately 225(50) A. Magnetic susceptibility and neutron diffraction experiments suggest a spin-glass ground state for InVO{sub 3}. - Graphical abstract: In situ powder X-ray diffractograms for the reduction of InVO{sub 4} in CO/CO{sub 2}. The three temperature regions show the conversion of InVO{sub 4} to InVO{sub 3} and final decomposition into In{sub 2}O{sub 3} and V{sub 2}O{sub 3}.

• OSTI ID: 20900900
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 12 Vol. 179; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
CARBON DIOXIDE
CRYSTAL STRUCTURE
DECOMPOSITION
GROUND STATES
INDIUM IONS
INDIUM OXIDES
MAGNETIC SUSCEPTIBILITY
MAGNETISM
NEUTRON DIFFRACTION
POLYCRYSTALS
REDUCTION
SPACE GROUPS
SPIN GLASS STATE
SYNTHESIS
THERMAL GRAVIMETRIC ANALYSIS
VANADATES
VANADIUM IONS
VANADIUM OXIDES
X-RAY DIFFRACTION