Quasistatic interpretation of the He- and Ne-induced blue asymmetry of the 326.1-nm Cd line shapes in the core and near-wing regions
Journal Article
·
· Physical Review. A
- Instytut Fizyki, Uniwersytet Mikolaja Kopernika, ul. Grudziadzka 5/7, 87-100 Torun (Poland)
A blue line shape asymmetry near the center of the Cd 326.1-nm line induced by low-polarizability perturbers (He, Ne) is explained by including the quasistatic contributions to the broadening rate associated with free-free transitions between repulsive branches of potential curves. The resulting shape in the near blue wing is represented by the addition to the Lorentzian and dispersion profiles of a quasistatic component. It is shown that for heavy perturbers (Ar, Kr, Xe) the quasistatic contributions play a marginal role near the line center and the line shape asymmetry arises mainly due to the finite duration of collision. It is also shown that for light perturbers (He, Ne) the quasistatic contributions are much more significant than those due to the collision duration and can adequately describe the blue asymmetry in the core region.
- OSTI ID:
- 20853077
- Journal Information:
- Physical Review. A, Journal Name: Physical Review. A Journal Issue: 2 Vol. 74; ISSN 1050-2947; ISSN PLRAAN
- Country of Publication:
- United States
- Language:
- English
Similar Records
A near-wing correction to the quasistatic far-wing line shape theory
Extension of the quasistatic far-wing line shape theory to multicomponent anisotropic potentials
Experimental A /sup 2/Pi potentials for Li-He and Li-Ne molecules
Journal Article
·
Mon Feb 14 23:00:00 EST 1994
· Journal of Chemical Physics; (United States)
·
OSTI ID:5191417
Extension of the quasistatic far-wing line shape theory to multicomponent anisotropic potentials
Journal Article
·
Wed Jun 15 00:00:00 EDT 1994
· Journal of Chemical Physics; (United States)
·
OSTI ID:7307602
Experimental A /sup 2/Pi potentials for Li-He and Li-Ne molecules
Journal Article
·
Wed Sep 01 00:00:00 EDT 1982
· Phys. Rev. A; (United States)
·
OSTI ID:6791697