Small-volume, ultrahigh-vacuum-compatible high-pressure reaction cell for combined kinetic and in situ IR spectroscopic measurements on planar model catalysts

Journal Article · Thu Dec 15 04:00:00 EST 2005 · Review of Scientific Instruments

DOI:https://doi.org/10.1063/1.2140449· OSTI ID:20778487

Zhao, Z; Diemant, T; Haering, T; Rauscher, H; Behm, R J ^[1]

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1. Department Surface Chemistry and Catalysis, University of Ulm, D-89069 Ulm (Germany)

We describe the design and performance of a high-pressure reaction cell for simultaneous kinetic and in situ infrared reflection (IR) spectroscopic measurements on model catalysts at elevated pressures, between 10{sup -3} and 10{sup 3} mbars, which can be operated both as batch reactor and as flow reactor with defined gas flow. The cell is attached to an ultrahigh-vacuum (UHV) system, which is used for sample preparation and also contains facilities for sample characterization. Specific for this design is the combination of a small cell volume, which allows kinetic measurements with high sensitivity under batch or continuous flow conditions, the complete isolation of the cell from the UHV part during UHV measurements, continuous temperature control during both UHV and high-pressure operation, and rapid transfer between UHV and high-pressure stage. Gas dosing is performed by a designed gas-handling system, which allows operation as flow reactor with calibrated gas flows at adjustable pressures. To study the kinetics of reactions on the model catalysts, a quadrupole mass spectrometer is connected to the high-pressure cell. IR measurements are possible in situ by polarization-modulation infrared reflection-absorption spectroscopy, which also allows measurements at elevated pressures. The performance of the setup is demonstrated by test measurements on the kinetics for CO oxidation and the CO adsorption on a Au/TiO{sub 2}/Ru(0001) model catalyst film at 1-50 mbar total pressure.

• OSTI ID: 20778487
• Journal Information: Review of Scientific Instruments, Journal Name: Review of Scientific Instruments Journal Issue: 12 Vol. 76; ISSN 0034-6748; ISSN RSINAK
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ABSORPTION SPECTROSCOPY
ADSORPTION
CATALYSTS
CHEMICAL REACTORS
DESIGN
GAS FLOW
GOLD
MASS SPECTROMETERS
MODULATION
OPERATION
OXIDATION
PERFORMANCE
POLARIZATION
REFLECTION
RUTHENIUM
SAMPLE PREPARATION
SENSITIVITY
TEMPERATURE CONTROL
TITANIUM OXIDES